Table of Contents
Laser Chemistry
Volume 6, Issue 6, Pages 373-380
http://dx.doi.org/10.1155/LC.6.373

The Investigation of Dissociation of Trifluoroacetyl Fluoride in the Field of Pulsed CO2 Laser

Institute of Stable Isotopes, State Committee on the Uses of Atomic Energy, Tbilisi 380086, Georgia

Received 15 November 1984; Accepted 13 August 1985

Copyright © 1986 Hindawi Publishing Corporation. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

Abstract

CF3COF dissociation channels in the pressure region from 0.2 to 4 Torr under the pulsed CO2 laser radiation are investigated. The dissociation products COF2, C2F6, and CF4 are identified according to the infrared spectra, and their relative output is measured over the whole range of the initial substance pressures. A scheme of laserochemical reactions describing the trifluoroacetyl fluoride dissociation channels is presented. The correctness of the chosen scheme is confirmed on the basis of the elementary theory of active collisions. The measurements of CF3COF dissociation selectivity for 18O and 13C are given.