Table of Contents
Laser Chemistry
Volume 10, Issue 5-6, Pages 367-376
http://dx.doi.org/10.1155/1990/32023

Reactive Bimolecular Collisions Studied With Combined Pulsed Lasers and Pulsed, Crossed, Supersonic Molecular Beams

URA 348 CNRS: Photophysique et Photochimie Moléculaire, Université Bordeaux I, Talence cedex 33405, France

Received 30 March 1990; Accepted 30 April 1990

Copyright © 1990 Hindawi Publishing Corporation. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

Abstract

Pulsed, supersonic molecular beams and pulsed lasers are particularly well matched tools when combined in molecular reaction dynamics studies. Salient features of an experiment using two pulsed molecular beam sources, a pulsed ultra-violet laser for creating reactive atoms by laser ablation and a pulsed dye laser for performing laser-induced fluorescence detection of the products are described. Differences with steady-state molecular beam experiments are outlined with respect to the following points: facility of inverting the data, possibility of obtaining high signal-to-background ratios and wide ranges of collision energy. These points are illustrated with some results concerning the reactions:C(n3P)J+NO(Xπr2)CN(X2Σ2)+O(n3PJ),C(n3PJ)+N2O(X1Σ+)CN(X2Σ+)+NO(Xπr2)and Mg(n1S0)+N2O(X1Σ+)MgO(X1Σ+)+N2(X1Σg+)