Table of Contents
Laser Chemistry
Volume 11, Issue 2, Pages 95-98
http://dx.doi.org/10.1155/LC.11.95

Preliminary Study on Kinetic Energy Distributions of Ar+ Fragments Resulting From Ar3+ Visible Photodissociation

Laboratoire de Physique Quantique (U.R.A. n° 505), Université Paul Sabatier, 118, route de Narbonne, Toulouse Cedex 31062, France

Received 29 March 1991; Accepted 29 April 1991

Copyright © 1991 Hindawi Publishing Corporation. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

Abstract

According to a strategy which involves DIM excitonic Hamiltonian, DIM-like transition dipole moments, realistic dynamical propagations with the HWD method (Hemiquantal dynamics with the Whole DIM basis), and the Wigner function to weight the initial conditions, a non-empirical theoretical study of the kinetic energy distribution of the Ar+ photofragments is performed for three total energies. The results illustrate the dominant symmetric stretching motion and the importance of non-adiabatic effects in the Ar3+ dissociation dynamics.