Table of Contents
Laser Chemistry
Volume 12, Issue 1-2, Pages 33-42
http://dx.doi.org/10.1155/LC.12.33

Laser-Induced Charge Transfer Under Crossed-Beam Conditions: Application to the Na + I2 → Na+ + I2 System

1Departamento de Química Física, Facultad de Ciencias Químcas, Universidad Complutense de Madrid, Madrid 28040, Spain
2Unidad de Haces Moleculares y Láseres, Centro de Estudios Avanzados Complutense, C/ Isaac Peral, s/n, Madrid 28040, Spain

Received 13 June 1991; Accepted 15 October 1991

Copyright © 1992 Hindawi Publishing Corporation. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

Abstract

A crossed-beam charge transfer study was carried out for the Na(32P3/2,1/2) + I2 → Na+ + I2 system using laser excitation of the Na atom. The excitation functions were measured for the title reaction, searching for spin orbit effects. A common energy threshold of E0≃0.23eV was found for both processes. In addition, similar post-threshold laws for each spin-orbit state indicate the absence of such effects over the low collision energy range.