Channels of Product Formation and Excited Molecules Relaxation at
Multiphoton Dissociation of Chlorodifluoromethane
V. A. Dimand,1K. K. Maltzev,1A. A. Nadeikin,1A. I. Nikitin,1A. M. Velichko,1and A. V. Vnukov1
Received19 Feb 1992
Abstract
C2F4, molecules have been for the first time directly proved to be generated in the reaction of
vibrationally-excited molecules CF2HCl. The contribution of this reaction to CF2HCl multiphoton
dissociation (MPD) products formation was shown to become predominant at the initial CF2HCl pressures
about ten Torr. Also fast relaxation of the highly excited molecules CF2HCl on the product molecules
C2F4 was discovered.