Laser Chemistry

Laser Chemistry / 1994 / Article
Special Issue

Recent Advances in Laser Molecular Spectroscopy of Polyatomic Molecules and Small Clusters: Part 2

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Open Access

Volume 14 |Article ID 034542 | https://doi.org/10.1155/1994/34542

Kaoru Yamanouchi, Jun Miyawaki, Soji Tsuchiya, David M. Jonas, Robert W. Field, "New Scheme for Extracting Molecular Dynamics from Spectra: Case Study on Vibrationally Highly Excited Acetylene", Laser Chemistry, vol. 14, Article ID 034542, 8 pages, 1994. https://doi.org/10.1155/1994/34542

New Scheme for Extracting Molecular Dynamics from Spectra: Case Study on Vibrationally Highly Excited Acetylene

Received26 May 1993

Abstract

Three types of analyses: generalized conventional spectroscopic analysis, statistical analysis, and hierarchical analysis, by which we aim to extract dynamical information from the complex spectrum of small polyatomic molecules are reviewed by referring to recent studies on vibrationally highly excited acetylene. A convolution analysis, one type of hierarchical analysis, is performed on the dispersed fluorescence spectrum of acetylene to demonstrate its practical applicability. Based on previous studies, as well as on the convolution analysis, a systematic and efficient procedure to treat such complex spectra is discussed.

Copyright © 1994 Hindawi Publishing Corporation. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.


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