Table of Contents
Laser Chemistry
Volume 15, Issue 2-4, Pages 229-247
http://dx.doi.org/10.1155/1995/28981

Proton Tunneling In 5-Chlorotropolone-M1 (M = Kr, Xe, CH4) Van Der Waals Complexes

Institute of Advanced Material Study and Department of Molecular Science and Technology, Graduate School of Engineering Sciences, Kyushu University, Kasuga-shi, Fukuoka 816, Japan

Received 11 March 1994

Copyright © 1995 Hindawi Publishing Corporation. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

Abstract

The S1-S0 fluorescence excitation spectra of 5-chlorotropolone-M1 (M = Kr, Xe, CH4) van der Waals (vdW) complexes in the region near the electronic origin have been measured in a supersonic free jet to investigate the effect of the vdW interactions on proton tunneling. Tunneling splittings have been observed in the vdW vibrations as well as in the 000 transitions of the Kr and Xe complexes. The 000 tunneling splitting of the 5-chlorotropolone-(CH4)1 complex is significantly smaller than those of the Kr and Xe complexes. It has been suggested that the vdW vibrations couple with intramolecular motions, leading to a higher potential energy barrier to tunneling in the CH4 complex. The results of the 5- chlorotropolone complexes have been compared to those of the tropolone complexes.