Vibrational Mode Coupling
to Reverse Electron Transfer
in (CN)<sub>5</sub>FeCNRu<mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML"><mml:mrow><mml:msubsup><mml:mrow><mml:mrow><mml:mo>(</mml:mo><mml:mrow><mml:msub><mml:mrow><mml:mtext>NH</mml:mtext></mml:mrow><mml:mtext>3</mml:mtext></mml:msub></mml:mrow><mml:mo>)</mml:mo></mml:mrow></mml:mrow><mml:mn>5</mml:mn><mml:mo>−</mml:mo></mml:msubsup></mml:mrow></mml:math> in Solution

Wang, Chengfei; Akhremitchev, Boris; Walker, Gilbert C.

doi:https://doi.org/10.1155/1999/41464

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Proceedings of the Eighth Conference on Time-Resolved Vibrational Spectroscopy

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Volume 19 | Article ID 041464 | https://doi.org/10.1155/1999/41464

Vibrational Mode Coupling to Reverse Electron Transfer in (CN)₅FeCNRu(NH3)5− in Solution

Chengfei Wang,¹Boris Akhremitchev,¹and Gilbert C. Walker¹

Received07 Apr 1997

Abstract

We present charge transfer absorption, resonance Raman and time-resolved infrared spectral data for (CN)₅FeCNRu(NH3)5− in various solvents. The transient infrared spectra and anisotropies reveal both non-equilibrium vibrational populations of high frequency modes and local solvent heating.

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Copyright © 1999 Hindawi Publishing Corporation. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

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Laser Chemistry

Proceedings of the Eighth Conference on Time-Resolved Vibrational Spectroscopy

Vibrational Mode Coupling to Reverse Electron Transfer in (CN)5FeCNRu(NH3)5− in Solution

Abstract

Copyright

Vibrational Mode Coupling to Reverse Electron Transfer in (CN)₅FeCNRu(NH3)5− in Solution