Proceedings of the Eighth Conference on Time-Resolved Vibrational SpectroscopyView this Special Issue
R. Anandhi, G. Balakrishnan, P. Mohandas, S. Umapathy, "Structure-Reactivity Correlations of Excited States of Perfluorinated Compounds: A Time Resolved Raman Study", Laser Chemistry, vol. 19, Article ID 068497, 6 pages, 1999. https://doi.org/10.1155/1999/68497
Structure-Reactivity Correlations of Excited States of Perfluorinated Compounds: A Time Resolved Raman Study
This paper reports the TR3 spectral studies on perfluorinated organic systems with the objective to understand the influence of perfluorination on the excited states. We have recorded the TR3 spectra and Raman excitation profiles of the triplet excited states of decafluorobenzophenone and fluoranil. It is found that the influence of perfluorination is more pronounced in the triplet excited state than the ground state and thus leads to enhanced reactivity for perfluorinated compounds through larger structural distortions.
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