Laser Chemistry

Laser Chemistry / 1999 / Article
Special Issue

Proceedings of the Eighth Conference on Time-Resolved Vibrational Spectroscopy

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Open Access

Volume 19 |Article ID 95804 | 5 pages | https://doi.org/10.1155/1999/95804

Vibrational Dynamics in Molecular Condensed Phases With The Clio Free Electron Laser

Received07 Apr 1997

Abstract

Single color pump-probe and photon-echo experiments have been performed on the CO stretching mode of W(CO)6 at about 1983 cm-1 in various liquids and solid environments. Combined with absorption data, the measured T1 and T2 times suggest the following conclusions: in all liquids studied, the IR absorption band is homogeneously broadened, whereas, inhomogeneous broadening is observed in solid matrices and in a xerogel. At low temperature, the echo decay is much faster in methane than in argon host.

Copyright © 1999 Hindawi Publishing Corporation. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.


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