Multianalytical Study of Laser Pulse Duration Effects in the IR Laser Cleaning of Wall Paintings from the Monumental Cemetery of Pisa

Andreotti, A.; Colombini, M. P.; Nevin, A.; Melessanaki, K.; Pouli, P.; Fotakis, C.

doi:https://doi.org/10.1155/2006/39046

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Lasers in the Preservation of Cultural Heritage

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Research Article | Open Access

Volume 2006 | Article ID 039046 | https://doi.org/10.1155/2006/39046

Multianalytical Study of Laser Pulse Duration Effects in the IR Laser Cleaning of Wall Paintings from the Monumental Cemetery of Pisa

A. Andreotti,¹M. P. Colombini,¹A. Nevin,^2,3K. Melessanaki,²P. Pouli,²and C. Fotakis^2,4

Academic Editor: Wolfgang Kautek

Received15 Sept 2006

Revised13 Dec 2006

Accepted13 Dec 2006

Published27 Feb 2007

Abstract

The feasibility of laser cleaning for the removal of a variety of surface deposits from fragments of real wall paintings from the monumental cemetery of Pisa using Nd:YAG at 1064 nm at (μs), (ns), and (ps) regimes is presented. Multianalytical investigations of the samples from irradiated surfaces of fragments were carried out in order to characterize the original and added materials and to detect any laser-induced alterations; analysis included scanning electron microscopy (SEM), Fourier transform infrared spectroscopy (FTIR), laser-induced breakdown spectroscopy (LIBS), pyrolysis-gas chromatography-mass spectrometry (PY-GC-MS), and gas chromatography-mass spectrometry (GC-MS). The presence of nitrocellulose and pure lead contaminations on the surface of the samples has been identified. Assessment of the laser cleaning has highlighted the importance of the optimization of laser parameters, specifically pulse duration and fluence at the specified wavelength.

References

B. Luk'yanchuk, Laser Cleaning, World Scientific, Singapore, 2002.
View at: Google Scholar
M. I. Cooper, Laser Cleaning in Conservation: An Introduction, Butterworth-Heinemann, Oxford, UK, 1998.
View at: Google Scholar
C. Fotakis, D. Anglos, S. Georgiou, V. Tornari, and V. Zafiropulos, Lasers in the Preservation of Cultural Heritage; Principles and Applications, edited by R. G. W. Brown and E. R. Pike, Taylor and Francis, New York, NY, USA, 2006.
View at: Google Scholar
L. Shekede, “Lasers: a preliminary study of their potential for the cleaning and uncovering of wall paintings,” in Restauratorenblätter, Sonderband - Lacona I, Laser in the Conservation of Artworks, pp. 51–56, Mayer, Vienna, Austria, 1997.
View at: Google Scholar
E. Dragasi, N. Minos, P. Pouli, C. Fotakis, and A. Zanini, “Laser cleaning studies on wall paintings; a preliminary study of various laser cleaning regimes,” to apper in Proceedings of Lasers in the Conservation of Artworks, LACONA 6.
View at: Google Scholar
P. Pouli, D. C. Emmony, C. E. Madden, and I. Sutherland, “Analysis of the laser-induced reduction mechanisms of medieval pigments,” Applied Surface Science, vol. 173, no. 3-4, pp. 252–261, 2001.
View at: Publisher Site | Google Scholar
M. Chappé, J. Hildehagen, K. Dickmann, and K. Bredol, “Laser irradiation of medieval pigments at IR, VIS and UV wavelengths,” Journal of Cultural Heritage, vol. 4, supplement 1, pp. 264–270, 2003.
View at: Publisher Site | Google Scholar
V. Zafiropoulos, C. Balas, and A. Manousaki et al., “Yellowing effect and discoloration of pigments: experimental and theoretical studies,” Journal of Cultural Heritage, vol. 4, supplement 1, pp. 249–256, 2003.
View at: Publisher Site | Google Scholar
M. Lassithiotaki, A. Athanassiou, D. Anglos, S. Georgiou, and C. Fotakis, “Photochemical effects in the UV laser ablation of polymers: implications for laser restoration of painted artworks,” Applied Physics A: Materials Science and Processing, vol. 69, no. 3, pp. 363–367, 1999.
View at: Publisher Site | Google Scholar
G. Bounos, A. Athanassiou, D. Anglos, S. Gheorgiou, and C. Fotakis, “Product formation in the laser irradiation of doped poly(methyl methacrylate) at 248 nm: implications for chemical effects in UV ablation,” Journal of Physical Chemistry B, vol. 108, no. 22, pp. 7052–7060, 2004.
View at: Publisher Site | Google Scholar
V. Zafiropulos, “Laser ablation in cleaning of artworks,” in Laser Cleaning, B. Luk'yanchuk, Ed., chapter 8, pp. 343–392, World Scientific, Singapore, 2002.
View at: Google Scholar
P. Pouli, G. Bounos, S. Georgiou, and C. Fotakis, “Femtosecond laser cleaning of painted artefacts; is this the way forward?,” to appear in Proceedings of Lasers in the Conservation of Artworks, LACONA 6.
View at: Google Scholar
P. Bracco, G. Lanterna, and M. Matteini et al., “Er: YAG laser: an innovative tool for controlled cleaning of old paintings: testing and evaluation,” Journal of Cultural Heritage, vol. 4, supplement 1, pp. 202–208, 2003.
View at: Publisher Site | Google Scholar
M. P. Colombini, A. Andreotti, G. Lanterna, and M. Rizzi, “A novel approach for high selective micro-sampling of organic painting materials by Er: YAG laser ablation,” Journal of Cultural Heritage, vol. 4, supplement 1, pp. 355–361, 2003.
View at: Publisher Site | Google Scholar
I. Bonaduce and M. P. Colombini, “Characterisation of beeswax in works of art by gas chromatography—mass spectrometry and pyrolysis—gas chromatography—mass spectrometry procedures,” Journal of Chromatography A, vol. 1028, no. 2, pp. 297–306, 2004.
View at: Publisher Site | Google Scholar
A. Andreotti, I. Bonaduce, M. P. Colombini, G. Gautier, F. Modugno, and E. Ribechini, “Combined GC/MS analytical procedure for the characterization of glycerolipid, waxy, resinous, and proteinaceous materials in a unique paint microsample,” Analytical Chemistry, vol. 78, no. 13, pp. 4490–4500, 2006.
View at: Publisher Site | Google Scholar
D. Anglos, “Laser-induced breakdown spectroscopy in art and archaeology,” Applied Spectroscopy, vol. 55, no. 6, pp. 186A–205A, 2001.
View at: Publisher Site | Google Scholar
D. Anglos, “Laser-Induced Breakdown Spectroscopy (LIBS): cultural heritage applications,” in Lasers in the Preservation of Cultural Heritage; Principles and Applications, R. G. W. Brown and E. R. Pike, Eds., chapter 3, pp. 53–94, Taylor and Francis, New York, NY, USA, 2006.
View at: Google Scholar

Copyright

Copyright © 2006 A. Andreotti et al. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

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