Table of Contents
Metal-Based Drugs
Volume 7, Issue 1, Pages 1-5
http://dx.doi.org/10.1155/MBD.2000.1

Synthetic, Spectroscopic and Biocidal Aspects of Heterobimetallic Complexes Comprising Platinum(II) and a Group Four or Fourteen Element

Department of Chemistry, University of Rajasthan, Jaipur 302004, India

Received 24 August 1999; Accepted 27 September 1999

Copyright © 2000 Hindawi Publishing Corporation. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

Abstract

Heterobimetallic complexes with varying amines have been synthesized by the reaction of [Pt(C2H8N2)2]Cl2 with group four or fourteen organometallic dichlorides, viz., R2MCl2 and Cp2M'Cl2 in a 1:2 molar ratio in MeOH (where M=Si or Sn, M'= Ti or Zr and R=Ph or Me). These complexes have been characterized by elemental analysis, molecular weight determinations, magnetic measurements, conductance, IR, H1 NMR and electronic spectra. The spectral data suggest a square planar geometry for all the complexes. Conductivity data suggest that they behave as electrolytes. These monometallic precursors along with their complexes have been screened in vitro against a number of pathogenic fungi and bacteria to assess their growth inhibiting potential.