Kinetic and High-Pressure Mechanistic Investigation of the Aqua Substitution in the Trans-Aquaoxotetracyano Complexes of Re(V) and Tc(V): Some Implications for Nuclear Medicine
Figure 3
The effect of pressure on the second-order
formation rate constant for the reaction between [TcO(OH2)(CN)4]− and NCS−, NNDMTU, and TU at 25°C, pH = 0.6, [M] = M, nm, a refers to left axis, b refers to the right axis. [NCS−] = 0.2 M, [NNDMTU] = [TU] =
0.05 M, μ =
1.0 M (NaNO3).