Modelling and Simulation in Engineering

Volume 2016, Article ID 3823047, 7 pages

http://dx.doi.org/10.1155/2016/3823047

## Modelling of Creep and Stress Relaxation Test of a Polypropylene Microfibre by Using Fraction-Exponential Kernel

Dipartimento di Scienze e Metodi dell’Ingegneria (DISMI), Università di Modena e Reggio Emilia, 42122 Reggio Emilia, Italy

Received 4 December 2015; Accepted 4 May 2016

Academic Editor: Julius Kaplunov

Copyright © 2016 Andrea Sorzia. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

#### Abstract

A tensile test until breakage and a creep and relaxation test on a polypropylene fibre are carried out and the resulting creep and stress relaxation curves are fit by a model adopting a fraction-exponential kernel in the viscoelastic operator. The models using fraction-exponential functions are simpler than the complex ones obtained from combination of dashpots and springs and, furthermore, are suitable for fitting experimental data with good approximation allowing, at the same time, obtaining inverse Laplace transform in closed form. Therefore, the viscoelastic response of polypropylene fibres can be modelled straightforwardly through analytical methods. Addition of polypropylene fibres greatly improves the tensile strength of composite materials with concrete matrix. The proposed analytical model can be employed for simulating the mechanical behaviour of composite materials with embedded viscoelastic fibres.

#### 1. Introduction

Fibre-reinforced composite materials consist of fibres with high strength and elastic modulus embedded in a matrix to produce a combination of properties that cannot be achieved by single constituents. Usually, fibres are the principal load-carrying members, while the surrounding matrix keeps them in the desired location and orientation. The matrix acts as a load transfer medium between fibres and plays a number of useful functions, for example, protecting the fibres from environmental damage. Fibres may be made up of various materials, such as steel, polymer, glass, or carbon, whereas polymer, metal, or ceramic can be chosen for the matrix material.

Fibre-reinforced polymer composites are probably the most important and widespread fibre-reinforced materials used for commercial and industrial applications. This is due to the combination of their low density, strength-weight ratios, and modulus-weight ratios that make them more attractive than many traditional metallic materials [1].

A classic example of fibre-reinforced composite used in civil engineering is Fibre-Reinforced Concrete (FRC), widely adopted for industrial pavements, tunnel linings, marine structures, earthquake-resistant structures, and plate and slab foundation [2]. In FRC composites, fibres are commonly added to concrete mixture in random disposition and short cuts in order to increase the cracking behaviour of concrete, thus transforming concrete from brittle into a ductile material [3]. However, there are composite materials in which fibres are aligned along particular directions, as it occurs in FRP frame elements (these composites can be studied by adopting, for instance, the approaches proposed in [4, 5]).

Recently, the use of macro synthetic fibres made of polymeric materials has been proposed for structural purposes [6, 7]. Experimental tests performed by Lanzoni et al. [8] show that the addition of polypropylene-based draw-wired fibres significantly improves crack resistance of the concrete mixture and enhances toughness and durability of FRC structural elements. Fibres could be found in interesting applications as an additive to improve concrete under aggressive environments (the mechanical behaviour has been studied under high thermal loads also [9, 10] and nuclear radiation [11]). However, particularly in such harsh conditions, a wide class of additives can be inserted at the mixing stage (like fly ash) to increase resistance of the concrete mixture [12].

Ductility and flexural strength of FRC are defined by energy-dissipation mechanisms during the pullout of the fibres that occurs in the opening propagating cracks [13, 14].

Pullout of the fibres begins after cracking the concrete matrix (for the stress and strain localizations at the crack tip, see, e.g., [14–17]) and ceases with the complete extraction of the fibres and its evolution depends on the bonding between fibre and matrix [18, 19]. Nevertheless due to their chemical inertness, polypropylene (PP) synthetic fibres have poor adhesion to the cement matrix with respect to other kinds of fibres. However, special surface nanotreatment can actually increase the adhesion properties between concrete and synthetic fibres, as shown by Di Maida et al. [3]. In this case, PP fibres may experience significant loading and consequently the viscous deformations of the composite material may considerably increase (for time-dependent effects in concrete structures see [20–22]). A single fibre can be studied as an embedded cylindrical body or a viscoelastic circular nanobeam in frictional contact with the cement matrix under axial tensile load (e.g., [23–25]).

Another application of synthetic fibres in civil engineering is the fibre-reinforced polymer (FRP) composites for reinforcement and retrofitting of concrete and masonry members, with applications in new buildings as well as for strengthening and/or rehabilitation of existing (prestressed as well as nonprestressed) structural members of both prefabricated and cast-in-place frames. FRP reinforcement consists in strengthening fibres applied to structural elements by a cementitious or polymeric-based layer. The mechanical performances of such systems can be assessed by solving the contact problem between two bounded layers [26–28] where the adhesive layer is a fibre-reinforced composite material [29] or, in a simpler way, as a fibre-reinforced Kirchhoff plate [30].

This work presents a creep and stress relaxation test performed over a PP synthetic fibre used for FRC. Creep is a time-dependent deformation of a viscoelastic material under the application of a constant stress at a constant temperature. Relaxation is the counterpart of creep, namely, a time-dependent stress of a viscoelastic material under the application of a constant deformation at a constant temperature. Both are complex phenomena for they depend on material properties (e.g., molecular orientation and crystallinity) and external conditions (e.g., applied stress, temperature, and moisture). Moreover, the viscoelastic behaviour of PP fibres embedded in an elastic matrix complicates the modelling of creep and stress relaxation response of the composite material, which depends on many additional parameters such as concentration, aspect ratio, orientation, and, obviously, mechanical properties of PP fibres.

Creep and stress relaxation tests best demonstrate the viscoelastic characteristics of a polymeric solid. In creep test, a constant stress is maintained on a specimen while its deformation is monitored as a function of time, and deformation increases with time. In stress relaxation test, a constant deformation is maintained while the stress on the specimen is monitored as a function of time, and stress decreases with time. Typical creep and stress relaxation diagrams exhibit an instantaneous elastic response followed by a delayed time-dependent response [1].

Over the experimental creep and stress relaxation tests performed, this paper proposes an analytical model to fit these experimental curves. The model uses fraction-exponential kernel in the viscoelastic operator and was proposed, for the first time, by Scott Blair and Coppen [31, 32] and Rabotnov [33] independently.

The classical viscoelastic constitutive models represented by a combination of dashpots and springs are usually adopted for simulating creep behaviour of composite materials. However, the simplest ones (Maxwell and Kelvin-Voight) are not sufficiently flexible to match experimental data for real materials. The more complex ones, obtained from combination of different Maxwell and Kelvin-Voight models, require instead many parameters and do not allow obtaining inverse Fourier or Laplace transforms in closed form [34, 35]. Therefore, in the 50s of the last century, a viscoelastic stress-strain relation based on fractional derivative has been proposed. The fractional derivative model (FDM) is more flexible and requires a smaller number of parameters, so that their calibration is considerably simpler. The flexibility is due to the order of derivatives which can vary to obtain a constitutive law suitable for the considered material. In 1948 Rabotnov [33] suggested to use fraction-exponential operators that can describe experimental data of real materials with sufficient accuracy and allows one to obtain inverse Laplace transforms analytically [36]. Scott Blair and Coppen [31, 32] used fraction-exponential operators for description of viscoelastic properties of materials experimentally (see Rogosin and Mainardi [37]). Fraction-exponential functions in viscoelastic operators were used by many authors last decade. Detailed discussion can be found in the book of Podlubny [38]. Published broad surveys are, for example, [39–41].

The model developed in the present paper is able to describe the creep curve of a PP fibre carefully and it allows obtaining the creep and stress relaxation test response of a fibre composite material in closed form. Moreover, the adopted fraction-exponential operators can be efficiently employed for the homogenization of synthetic FRC by extending the Maxwell scheme developed for elastic composites to viscoelastic behaviour of the constituents (e.g., [34, 42]).

#### 2. Materials and Methods

##### 2.1. Material and Breaking Test

The fibre consists of PP monofilament with a diameter of 0.78 mm and length of 200 mm. Since the cross section of the fibre is not perfectly circular, the diameter is an average of six measurements: Two measurements in two orthogonal directions in three points of the fibre, namely, at the middle and at both ends. To evaluate elastic Young modulus and tensile strength, tensile tests were performed on four specimens of fibres until their breakage. Each fibre was clamped at its ends and pulled by an electromechanic traction machine under displacement control.

The load cell is a GALDABINI 514262 TYPE TCA, with OUTPUT sensitivity of 2 mV/V. The machine uses a 20-bit A/D converter to acquire the analogical quantities. The resolution of the load cell is 0.002 N over the entire field of use, with a capacity of 250 N. The displacement control was performed by the actuator at a rate of 40 mm/min. The average value of the breakage tensile load is 130.5 N that occurs approximately at a displacement of 10 mm, namely, at 5% of strain.

The elastic Young modulus (Table 1) was determined from the ratio between stress and strain. The stresses and strains were calculated based on the early stage of the experimental load-displacement curve averaged on the four fibres.