Table of Contents
Research Letters in Organic Chemistry
Volume 2008 (2008), Article ID 419054, 4 pages
Research Letter

C s 2 C O 3 /[bmim]Br as an Efficient, Green, and Reusable Catalytic System for the Synthesis of N-Alkyl Derivatives of Phthalimide under Mild Conditions

1Department of Chemistry, Faculty of Sciences, Persian Gulf University, Bushehr 75169, Iran
2Department of Chemistry, Faculty of Sciences, Payame Noor University (PNU), Bushehr 1698, Iran
3Department of Chemistry, College of Sciences, Shiraz University, Shiraz 71454, Iran

Received 6 July 2008; Accepted 2 November 2008

Academic Editor: Nicos Petasis

Copyright © 2008 Alireza Hasaninejad et al. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.


Aza-conjugate addition of phthalimide to 𝛼 , 𝛽 -unsaturated esters efficiently achieves in the presence of catalytic amount of C s 2 C O 3 and ionic liquid 1-butyl-3-methylimidazolium bromide ([bmim]Br) under mild reaction conditions ( 7 0 C ) to afford N-alkyl phthalimides in high yields and relatively short reaction times.