Abstract
The efficiency transfer (ET) principle is considered as a simple numerical simulation method, which can be used to calculate the full-energy peak efficiency (FEPE) of NaI(Tl) scintillation detector over a wide energy range. In this work, the calculations of FEPE are based on computing the effective solid angle ratio between a radioactive point and parallelepiped sources located at various distances from the detector surface. Besides, the attenuation of the photon by the source-to-detector system (detector material, detector end cap, and holder material) was considered and determined. This method is straightforwardly useful in setting up the efficiency calibration curve for NaI(Tl) scintillation detector, when no calibration sources exist in volume shape. The values of the efficiency calculations using theoretical method are compared with the measured ones and the results show that the discrepancies in general for all the measurements are found to be less than 6%.
1. Introduction
Determination of the absolute efficiency of NaI and Ge detectors has been a long standing problem in gamma-ray spectrometry and numerous reports have been published during the last decades as [1]. The calibration of gamma-ray detectors and sources is still laborious and time consuming and requires extensive operator experience [2]. Accurate calibrated photon emitting sources are difficult to prepare for all the geometrical arrangements used in gamma-ray spectroscopy and sometimes nonfeasible as, for example, in the case of metallic extended samples in neutron activation analysis [3]. In order to overcome the above problem, several nonexperimental methods have been proposed and applied, depending on the photon energy and source-detector geometry and volume [4]. An alternative possibility of being able to compute the efficiencies is thus highly desirable. One of the most common approaches, which only requires point source measurements, is called the efficiency transfer method and was pioneered by Moens et al. [5].
The efficiency transfer principle (ET) means the change in efficiency values under conditions of measurement different from those of calibration setup. It can be determined on the basis of variation of the geometrical parameters of the source-detector arrangement (effective solid angle ratio) [6]. In the previous group work, the efficiency transfer (ET) principle was used to determine the efficiency of the detector corresponding to different sample shapes at different distances from the detector surface [7]. The calculations of the effective solid angle ratio including the attenuation of any material between the source and the detector are based on the direct mathematical method, such as that reported in [8], which was successfully used to calibrate different detectors using different shapes radioactive sources.
In the present work, the efficiency transfer (ET) principle is used to calculate the full-energy peak efficiency (FEPE) of NaI(Tl) detector for axial radioactive parallelepiped sources based on the FEPE calibration for point source as a reference [9]. The calculations of the effective solid angle are based on new mathematical method reported by Hamzawy [10], where an expression to calculate the total efficiency was derivative of the cylindrical NaI(Tl) detector for using axis-off point and coaxial circular disc sources. These expressions are shorter than those in previous studies and easier to calculate, where they are in a form of an elliptical integrations type, which saves the program length and the running time and increases the accuracy of calculations [11].
2. Mathematical Viewpoint
The efficiency transfer principle as presented in [12] was applied to obtain the efficiency calibration curves of the gamma-ray detectors based on the following equation:where and are the detector (FEPE) for a reference source at another position and the effective solid angle subtended by the detector surface and the reference source at that position, respectively. In order to use the efficiency transfer principle, the experimental reference efficiency, , was essentially measured [13].
However, and are the detector (FEPE) for the target source and the effective solid angle subtended by the detector surface and the target source at that position, respectively.
Consider a cylindrical detector with radius, , length, , and a point source positioned at height, , from the detector surface and placed at a lateral distance from the detector axis, , smaller than the detector radius, as shown in Figure 1.
In this case, the effective solid angle can be calculated assuming that each photon emitted from the point source will pass through the detector active volume and will traverse distance, , until it emerges from the crystal. According to (2) and (3), two cases have to be considered:(i)The photon may enter from the detector surface and emerge from the detector base, covering distance, , given by(ii)The photon may enter from the detector surface and emerge from detector side, covering distance, , given by
The direction of the incident photon is defined by polar () and azimuthal () angles, where the azimuthal () angle takes the value from 0 to 2, while the polar angle () takes the two different steps based on the source-to-detector configuration and given bywhere and are the photon maximum polar angles for entering through the detector face and exiting from the detector base, respectively.
The effective solid angle, , in case of a nonaxial point source is given bywherewhere in (6) is the attenuation coefficient of the detector active material, while is the attenuation factor of the absorber layers with attenuation coefficients, , and with thickness, , between the source-to-detector systems; also, is the photon path lengths inside the absorber material.
If there is a parallelepiped source with dimensions (length), (width), and (height) as illustrated in Figures 2 and 3, the effective solid angle, , is given bywherewhile and are the self-attenuation factor of the source matrix and the attenuation factor of the container material, respectively, which can be represented by the following equations:where is the attenuation coefficient of the source matrix, where the source is filled with radioactive material, and is the attenuation coefficient of the source container material, while is the distance traveled by the emitted photon inside the source and is the distance traveled by the emitted photon inside the source container material.
The container wall thicknesses are , , and for the bottom, width, and length, respectively. Table 1 shows the possible path lengths traveled by the photon within the source matrix and the source container material, while Table 2 shows the values of the polar and azimuthal angles of the source matrix and the source container material.
The distance traveled inside the source matrix, , varies upon the variation of the polar and azimuthal angles inside the source itself, such as what is given in Table 3.
The distance traveled inside the source container material, , varies upon the variation of the polar and azimuthal angles inside the source itself and can be given in Table 4.
A computer program has been designed to calculate the effective solid angle ratio between point and parallelepiped sources located at various distances from the detector surface. The numerical computation of the double integrals is performed using the trapezoidal rule. Moreover, the accuracy of the integration increases by increasing the number of integration steps, . It was stated that integration converges very well at .
The full-energy peak efficiency (FEPE) can be calculated based on the reference measured full-energy peak efficiency [14] by the following formula:where and are the full-energy peak efficiency (FEPE) of the NaI(Tl) detector and the effective solid angles subtended by the detector surface for using an axial situated point source located at reference position from the detector surface, respectively. In this case, to obtain , at the axial position, the lateral distance, , must be equal to zero value in (3) and (4).
However, and are the full-energy peak efficiency (FEPE) of the NaI(Tl) detector and the effective solid angles subtended by the detector surface for using radioactive parallelepiped source located at any axial position different from the reference one, respectively.
3. Experimental Setup
The detector used in these measurements is NaI(Tl) detector (CANBERRA-802 series). The nominal dimensions of the detector crystal are 76.2 mm diameter and 76.2 mm length. It is mounted inside a protective aluminum end cap (0.5 mm thick, mass per unit area 147 mg/cm2) with its axis being vertical, reflector-oxide (1.6 mm thick, mass per unit area 88 mg/cm2), magnetic/light shield-conetic lined steel (typical operating voltages: cathode to anode +800 V dc, dynode to dynode +80 V dc, and cathode to dynode +150 V dc). The detector relative energy resolution is 8.5% at 662 keV. The signals from the detector were amplified and shaped by Osprey Universal Digital MCA Tube Base for Scintillation Spectrometry. The Osprey MCA designed to be temperature stabilized with NaI detector, standard with 14 pins using 10-stage PMTs, high performance, high-voltage power supply (HVPS), preamplifier, fully integrated MCA includes all needs to support spectrometry system for working in both laboratory and field. The MCA can be controlled through the USB cable to control the display, acquisition, and analysis process with the Genie 2000 software [15].
Two types of sources were used in the present experiment: standard point sources for the reference calibration and volume source as the target as of this study. The sources activities, their uncertainties, half-lives, photon energies, and photon emission probabilities per decay for all radionuclides used in the calibration process were listed in Tables 5 and 5.
The standard radioactive sources were purchased from Physikalisch-Technische Bundesanstalt (PTB). The radioactive substance is a very thin, compact grained layer applied to a circular area about 5 mm in diameter, in the middle of the source between two polyethylene foils each having a mass per unit area of mg·cm−2. By heating under pressure, the two foils are welded together over the whole area so that they are leak-proofed. To facilitate handling, the foil 26 mm in diameter is mounted in a circular aluminum ring (outer diameter: 30 mm, height: 3 mm) from which it can easily be removed if and when required. There are two types of the standard radioactive sources used in the present work; the first type was in the form of five point sources. These sources were measured using a homemade Plexiglas holder at 3 different axial distances from the detector surface (P4 = 20 cm, P6 = 30 cm, and P8 = 40 cm) and start from P4, while the second type of radioactive sources is parallelepiped which contains 152Eu solution. These radioactive parallelepiped sources were measured at two positions, on the Plexiglas holder base with thickness 0.363 cm at position P0 “placed directly on the detector end cap” and at position P1 = 5 cm from the detector surface.
4. Results and Discussion
In these measurements of low activity sources, the dead time was always less than 3%. So the corresponding factor is obtained simply using ADC live time. The peak areas, live time, real time, and starting time for each spectrum were entered in the spreadsheet used to calculate the efficiency curves [15]. Once the full-energy peak area is obtained, the full-energy peak efficiency values can be calculated by the following equation:where is the full-energy peak efficiency as a function of the photon energy, is the net peak area, is the radionuclide activity at the time of standardization (Bq), is the live time , is the photon emission intensity at energy , and are the correction factors due to dead time and radionuclide decay [15]. The experimental uncertainties on acquisition time and source distance were considered negligible; thus, the standard deviation on , , was determined by the uncertainties on , , and and was calculated according to the propagation of error law according to the following equation:
The relative uncertainty in the peak area was always arranged to be 0.5% and so the absolute uncertainty measurements were dominated by the uncertainty in the radionuclide activity. Uncertainties in the relative efficiency measurements with a given source as a function of distance were generally determined by a combination of counting statistics. Once the individual efficiencies have been obtained by applying the correction factors, the overall efficiency curve is obtained by fitting the experimental points to a polynomial logarithmic function of the fourth order using nonlinear least square fit. In this way, the correlation between data points from the same calibrated source has been included to avoid the overestimation of the uncertainty in the measured efficiency.
In the present work, the analytical formulae are considering the detector active volume and the effective geometrical solid angle, corresponding to a radioactive point and parallelepiped sources located at various distances from the detector surface in order to obtain a simple formula for the efficiency transfer method. In addition, the self-attenuation coefficient of the source matrix, the attenuation factors of the source container, and the detector housing materials are also treated by calculating the path length within these materials.
The reference experimental calibration curve was obtained by using radioactive point sources measured at three different axial distances from the detector surface, P4, P6, and P8, as represented in Figure 4. The efficiency transfer principle is used to convert the full-energy peak efficiency curve from these positions’ “reference curve” to the other (FEPE), which was located at positions P0 up to P1 for using radioactive parallelepiped sources V1 and V2 based on (12). In addition, the values of the effective solid angle are tabulated in Table 6 for a point and parallelepiped sources at the measurement positions. The relative deviation between the measured and the calculated efficiencies (FEPE) is given by the following equation:where and are the calculated and experimental efficiencies, respectively.
The FEPE values with their associated uncertainties for parallelepiped sources, V1 and V2, were measured at positions P0 and P1. These data are compared with the calculated values based on the conversion process by (12) from the reference efficiency curve for a point source at three different axial distances from the detector surface, and the comparisons are tabulated in Tables 7 and 8. In addition, the deviation percentage Δ%, between the measured and the calculated (FEPE) values at various positions is listed in the same tables.
5. Conclusion
This work provides an analytical method in gamma-ray spectrometry field and consider as useful tools of NaI(Tl) efficiency computation for laboratory routine measurements, saving the time and avoiding the experimental calibration process for different sample geometries when standard radioactive sources do not exist. Therefore, this method is sufficient for most routine measurement work under one condition, where one must be provided by exact knowledge of the geometrical parameters of the source-detector arrangements taking into account the attenuation of the gamma-rays by any material between the source and the detector like aluminum end cap, aluminum oxide reflector, and Plexiglas holder. The calculations were based on the efficiency transfer principle and a new straightforward analytical definition to compute the effective solid angle between the parallelepiped source and the detector surface.
Conflict of Interests
The authors declare that there is no conflict of interests regarding the publication of this paper.
Acknowledgment
The authors would like to express their gratitude for Professor Dr. Marie Christine Lépy, Laboratoire National Henri Becquerel-CEA (LNHB-CEA), Saclay, France, for the fruitful discussions.