Electrochemical Behavior and Determination of Rutin on Modified Carbon Paste Electrodes

Potentials of anodic (<svg height="16.237499" id="M5" style="vertical-align:-4.74141pt" version="1.1" viewbox="0 0 22.75 16.237499" width="22.75" xmlns="http://www.w3.org/2000/svg">
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<tspan style="font-size: 8.75px; " x="0" y="0">𝑝</tspan>
<tspan style="font-size: 8.75px; " x="4.2797279" y="0">𝑎</tspan>
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</svg>) and cathodic (<svg height="16.237499" id="M6" style="vertical-align:-4.74141pt" version="1.1" viewbox="0 0 22.3375 16.237499" width="22.3375" xmlns="http://www.w3.org/2000/svg">
<g transform="matrix(1.25,0,0,-1.25,0,16.2375)">
<g transform="translate(72,-59.01)">
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<tspan style="font-size: 12.50px; " x="0" y="0">𝐸</tspan>
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<tspan style="font-size: 8.75px; " x="0" y="0">𝑝</tspan>
<tspan style="font-size: 8.75px; " x="4.2797279" y="0">𝑐</tspan>
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</svg>) peak (versus Ag/AgCl, 1 M KCl), peak separation (<svg height="16.5625" id="M7" style="vertical-align:-4.74141pt" version="1.1" viewbox="0 0 28.5375 16.5625" width="28.5375" xmlns="http://www.w3.org/2000/svg">
<g transform="matrix(1.25,0,0,-1.25,0,16.5625)">
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<tspan style="font-size: 12.50px; " x="0" y="0">Δ</tspan>
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<text transform="matrix(1,0,0,-1,-54,60.4)">
<tspan style="font-size: 8.75px; " x="0" y="0">𝑝</tspan>
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</svg>), anodic peak current (<svg height="13.7625" id="M8" style="vertical-align:-3.22282pt" version="1.1" viewbox="0 0 11.1 13.7625" width="11.1" xmlns="http://www.w3.org/2000/svg">
<g transform="matrix(1.25,0,0,-1.25,0,13.7625)">
<g transform="translate(72,-60.99)">
<text transform="matrix(1,0,0,-1,-71.95,64.25)">
<tspan style="font-size: 12.50px; " x="0" y="0">𝑖</tspan>
</text>
<text transform="matrix(1,0,0,-1,-68.06,61.12)">
<tspan style="font-size: 8.75px; " x="0" y="0">𝑎</tspan>
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</svg>, the average from seven repeated measurements, standard deviation SD) and ratio of cathodic to anodic peak current (<svg height="14.7125" id="M9" style="vertical-align:-3.2316pt" version="1.1" viewbox="0 0 26.012501 14.7125" width="26.012501" xmlns="http://www.w3.org/2000/svg">
<g transform="matrix(1.25,0,0,-1.25,0,14.7125)">
<g transform="translate(72,-60.23)">
<text transform="matrix(1,0,0,-1,-71.95,63.5)">
<tspan style="font-size: 12.50px; " x="0" y="0">𝑖</tspan>
</text>
<text transform="matrix(1,0,0,-1,-68.06,60.37)">
<tspan style="font-size: 8.75px; " x="0" y="0">𝑐</tspan>
</text>
<text transform="matrix(1,0,0,-1,-63.49,63.5)">
<tspan style="font-size: 12.50px; " x="0" y="0">/</tspan>
<tspan style="font-size: 12.50px; " x="3.4758339" y="0">𝑖</tspan>
</text>
<text transform="matrix(1,0,0,-1,-56.13,60.37)">
<tspan style="font-size: 8.75px; " x="0" y="0">𝑎</tspan>
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</svg>) of 0.1 mM rutin at the paraffin/graphite (CPE), paraffin/iron-phthalocyanine/graphite (IP/CPE) and [hmim][Tf<sub>2</sub>N]/graphite (IL/CPE) electrodes (scan rate 100 mV s<sup>−1</sup>). 

The Scientific World Journal

tab1

Table 1

Table 1: Electrochemical Behavior and Determination of Rutin on Modified Carbon Paste Electrodes 