Table of Contents Author Guidelines Submit a Manuscript
The Scientific World Journal
Volume 2014, Article ID 307895, 6 pages
http://dx.doi.org/10.1155/2014/307895
Research Article

Cyanuric Chloride as an Efficient Catalyst for the Synthesis of 2,3-Unsaturated O-Glycosides by Ferrier Rearrangement

1College of Chemistry and Chemical Engineering, Xinxiang University, Xinxiang, Henan 453003, China
2School of Pharmacy, Xinxiang Medical University, Xinxiang, Henan 453003, China

Received 19 August 2013; Accepted 20 October 2013; Published 19 January 2014

Academic Editors: H. Miyabe, H. Pellissier, and I. Shibata

Copyright © 2014 Xiaojuan Yang and Na Li. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

Abstract

Cyanuric chloride has been found to be an efficient catalyst for the synthesis of 2,3-unsaturated O-glycosides from the reaction of 3,4,6-tri-O-acetyl-D-glucal and a wide range of alcohols in dichloromethane at room temperature. The experimental procedure is simple, and the products are obtained in high yields.