The Scientific World Journal / 2014 / Article / Tab 2

Research Article

Simulation for Supporting Scale-Up of a Fluidized Bed Reactor for Advanced Water Oxidation

Table 2

Reactions and rate constants for complete mineralization of phenol by Fe3+/Fe2+/H2O2.

No.ReactionRate constantReference

R11 × 10−2 M−1s−1[20, 35]
R23.3 × 105 M−1s−1[36]
R36.3 × 101 M−1s−1[35, 36]
R43.3 × 107 M−1s−1[36]
R58.3 × 105 s−1[37]
R64.2 × 109 s−1[35]
R73.3 × 109 M−1s−1[35]
R87.0 × 103 M−1s−1[35]
R97.0 × 103 M−1s−1[35]
R102.0 × 1010 M−1s−1[35]
R111.1 × 1010 M−1s−1[20]
R127.0 × 103 M−1s−1[35]
R13 + fumaric acid1.0 × 101 M−1s−1[35]
R14Fumaric acid + oxalic acid + CO26.0 × 109 M−1s−1[20]
R15Oxalic acid + CO21.4 × 106 M−1s−1[20]
R16Phenol + aromatics0.3805 M−1s−1[38]
R17Phenol + muconic acid1.933 × 10−2 M−1s−1[38]
R18Phenol + fumaric acid1.5 × 10−2 M−1s−1[39]
R19H2O20.0012 s−1From this study
R20TOC1 + TOC2 + H2O6.35 × 10−5 M−1s−1From this study
R21TOC2 + final product9.6 × 10−7 M−1s−1From this study

DHCD: di-hydroxy-cyclohexa-di-enyl radical; THB: tri-hydroxy-benzene; THCD: di-hydroxy-cyclohexa-di-enyl radical.