Research Article
Kinetics of NiO and NiCl2 Hydrogen Reduction as Precursors and Properties of Produced Ni/Al2O3 and Ni-Pd/Al2O3 Catalysts
Table 1
Reaction mechanisms and the corresponding equations.
| | Equations | Reaction mechanism |
| | | One-dimensional diffusion | | | Two-dimensional diffusion (cylindrical symmetry) | | | Three-dimensional diffusion (spherical symmetry, Jander equation) | | | Three-dimensional diffusion (spherical symmetry, Ginstling-Braunshtein equation) | | | First-order reaction (unimolecular decay law) | | | Random nucleation (Avrami I equation) | | | Random nucleation (Avrami II equation) | | | Phase-boundary controlled (cylindrical symmetry) | | | Phase-boundary controlled (spherical symmetry) |
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