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The Scientific World Journal
Volume 2017, Article ID 9690704, 15 pages
Research Article

H2S Loss through Nalophan™ Bags: Contributions of Adsorption and Diffusion

Department of Chemistry, Materials and Chemical Engineering “Giulio Natta”, Politecnico di Milano, Piazza Leonardo da Vinci 32, 20133 Milano, Italy

Correspondence should be addressed to Selena Sironi; ti.imilop@inoris.aneles

Received 8 March 2017; Revised 18 April 2017; Accepted 23 April 2017; Published 27 June 2017

Academic Editor: Ki-Hyun Kim

Copyright © 2017 Lidia Eusebio et al. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.


Hydrogen-sulfide (H2S) is a molecule of small dimensions typically present in the odor emissions from different plants. The European Standard EN 13725:2003 set a maximum storage time allowed of 30 hours, during which the sampling bag has to maintain the mixture of odorants with minimal changes. This study investigates the H2S losses through Nalophan bags and it shows that nonnegligible losses of H2S can be observed. The percent H2S loss after 30 hrs with respect to the initial concentration is equal to 33%  ± 3% at a relative humidity of 20% and equal to 22%  ± 1% at a relative humidity of 60%. The average quantity of adsorbed H2S at 30 h is equal to 2.17 105 at a storage humidity of 20% and equal to 1.79 105 at a storage humidity of 60%. The diffusion coefficients of H2S through Nalophan, for these two humidity conditions tested, are comparable (i.e., 7.5 10−12 m2/sec at 20% humidity and 6.6 10−12 m2/sec at 60% humidity).