Research Article

H2S Loss through Nalophan™ Bags: Contributions of Adsorption and Diffusion

Table 1

Scheme of the studies related to the pollutant loss through sampling bag.

Reference numberAuthor and yearPolymeric FilmThickness [µm]Chemical compoundDetection System

[1]Sironi et al., 2014Nalophan20NH3GC

[5]Y.-H. Kim and K.-H. Kim, 2012PEAn.d.Benzene, toluene, styrene, p-xylene, methyl ethyl ketone, methyl isobutyl ketone, isobutyl alcohol, butyl acetate, acetaldehyde, propionaldehyde, butyraldehyde, isovaleraldehyde, valeraldehydeGC
MS

[6] Laor et al., 2010Tedlarn.d.Odors emitted from municipal sewage, aeration basin, sludge, livestock manure, coffeeDO
Nalophan20

[7] Akdeniz et al., 2011Tedlarn.d.NH3, CH4, N2O, H2S, total sulfur dioxidepulsed fluorescence analyzer, chemiluminescence analyzer, GC
IR
FlexFoiln.d.

[8] Bakhtari, 2014Nalophan50Benzene, ozone, H2SDO
Tedlar50
Teflon50

[9] Beghi and Guillot, 2006Tedlar50Methanol, ethanol, acetone, n-propanol, n-hexane, dichloroethane, trichloroethane, methyl isobutyl ketone, toluene, butyl acetateGC
Teflon50
FlexFoil75

[10] Beghi and Guillot, 2008Nalophan20Acetone, n-propanol, ethanol, n-hexane, 1,2-dichloroethane, trichloroethane, methyl isobutyl ketone, toluene, butyl acetate, ethylbenzeneGC
Tedlar50

[11]Boeker et al., 2014 Nalophan n.d. Butylamine, ethylamine, carbon disulfide, dimethyl sulfide, butyl acetate, ethyl acetate, n-butyrate acetate, dichloroethane, chloroform, dichloromethane, 2-heptanone, methyl isobutyl ketone, ethyl methyl ketone, acetone, n-hexyl acetate, α-ionone, limonene, α-pinene, 1,2,3,4-tetraidronaphtene, ethylbenzene, toluene, skatole, indole, methanol, p-cresol, phenol, n-hexanol, n-butanol, ethanol, α-hexyl cinnamaldehyde, furfural, hexanalGC
MS
NaloSafen.d.
Nalobarn.d.
Tedlar n.d.

[12]Bokowa, 2012Tedlarn.d.2-Methylbutane, pentane, 2,2-dimethylbutane, 2-methylpentane, cyclopentane, 3-methylpentane, 1-hexene, hexane, 2,4-dimethylpentane, methylcyclopentane, 3-methyl-1-hexene, 3-methyl-1, 3-pentadiene, 2-methylhexane, 2,3-dimethyl pentane, cyclohexane, 3-methylhexane, benzene, cyclohexene, heptane, 2,5-dimethylhexane, methyl cyclohexane, ethyl cyclopentane, 2-methylpentane, 3-methylpentane, 2,3,5-trimetilesano, t-1,4-dimethylcyclohexane, toluene, octane, 1,1-dimethylcyclohexane, t-1,2-dimethylhexane, c-1,4-dimethylcyclohexane, propyl cyclopentane, c-1, 2-dimethylcyclohexane, 2 + 4-methyloctane, 3-methyloctane, ethylbenzene, nonane, m + p-xylene, 3,7-dimethyl-1-octene, o-xylene, cumene, propylbenzene, dean, 1,3,5-trimethylbenzene, 1,2,4-trimethyl benzene, p-cymene, 1,2,3-trimethyl benzene, undecane, dodecane, tridecane, tetradecaneGC
MS

[13] Cariou and Guillot, 2006Tedlar502-Propanolo, 2-butanone, tolueneGC

[14] Eusebio et al., 2016Nalophan20 μmH2Sspecific H2S sensors

[15] Guillot and Beghi, 2008Nalophan20H2S, H2OGC
Tedlar,50
Teflon,50
FlexFoil75

[16] Hansen et al., 2011Tedlar,50Carboxylic acids, phenols, indoles, sulfur compoundsGC
MS
Nalophan20

[17] Jo et al., 2012PEAn.d.H2S, methanethiol, carbon disulfide, SO2, dimethyl sulfide, dimethyl disulfideGC
Tedlarn.d.

[18] Kim, 2006Tedlarn.d.H2S, methanethiol, dimethyl sulfide, dimethyl disulfideGC
Polyestern.d.

[19] Kim et al., 2012PEA,50Benzene, toluene, p-xylene, styrene, methyl ethyl ketone, methyl isobutyl ketone, butyl acetate, isobutyl alcoholGC
MS
Tedlar50

[20] Koziel et al., 2005Tedlar,50Acetic acid, propionic acid, isobutyric acid, butyric acid, isovaleric acid, valeric acid, hexanoic acid, p-cresol, indole, 4-ethylphenol, 2-aminoacetophenoneGC
MS
Teflon,50
foil125
Melinex (PET)15

[21] Le et al., 2013Tedlarn.d.H2S, methanethiol, ethanethiol, dimethyl sulfide, tert-butanethiol, ethyl methyl sulfide, 1-butanethiol, dimethyl disulfide, diethyl disulfide, dimethyl trisulfideGC
Mylarn.d.
Nalophann.d.

[22] Le et al. 2015Tedlar50Hydrogen sulfide, methanethiol, ethanethiol, dimethyl sulfide, tert-butanethiol, ethyl methyl sulfide, 1-butanethiol, dimethyl disulfide, diethyl disulfide, dimethyl trisulfideGC
Mylar25
Nalophan25

[23] Mochalski et al., 2009Nalophan,20H2S, methanethiol, ethanethiol, carbonyl sulfide, dimethyl sulfide, carbon disulfide GC
MS
Tedlar transparent,50
Tedlar black,25
Teflon,n.d.
FlexFoiln.d.

[24]Mochalski et al., 2013 Tedlar 50 n-Butane, n-pentane, n-hexane, n-octane, n-decane, isobutane, 3-methyl pentane, 2-butene E and Z, 2-pentene E and Z, 1-hexene, methylcyclopentane, a-pinene, (+)-3-carene, p-cymene, D-limonene, eucalyptol, benzene, toluene, p-xylene, o-xylene, acetone, 2-butanone, 2-pentanone, 4-heptanone, 2-butenone, propanal, 2-methyl propanal, butanal, hexanal, octanal, 2-methyl-2-propenal, furan, 2-methyl furan, 2,5-dimethyl furan, thiophene, 3-methyl thiophene, methyl acetate, ethyl acetate, n-propyl acetate, methyl methacrylate, dimethyl selenide, ethyl ether, pyrimidine, acetonitrile, 2-methyl pentane, 4-methyl heptane, isoprene, ethylbenzene, dimethyl sulfide, 2-methyl-1-pentene, n-butyl acetate, 2,4-dimethyl heptane, 2,4-dimethyl-1-heptene, 4-methyl octane, 3-methyl furan, methyl propyl sulfideGC
MS
Kynar50.8
Flexfilm 76

[25] Parker et al., 2010Tedlarn.d.p-Cresol, acetic acid, propionic acid, isobutyric acid, butyric acid, isovaleric acid, valeric acid, hexanoic acidDO/GC-MS

[26] Sáiz et al., 2011Polyethylenen.d.DynamitesGC
MS
HPLC

[27] Sironi et al., 2014Nalophan20NH3GC

[28] Sironi et al., 2014Nalophan20NH3GC

[29] Sulyok et al., 2002Silcosteel cylindern.d.Methylmercaptan, ethylmercaptan, Dimethyl sulfide, 2-Propylmercaptan, 1-Propylmercaptan, 2-Butylmercaptan, 1-ButylmercaptanGC
Tedlarn.d.

[30] Sulyok et al., 2001Silcosteel cylindern.d.Methylmercaptan, ethylmercaptan, dimethyl sulfide, ethyl methyl sulfide, 2-propylmercaptan, 1-propylmercaptan, 2-butylmercaptan, diethyl sulfide, 1-butylmercaptanGC
Tedlar50
Tedlar black/clear layered50

[31] Trabue et al., 2006Tedlarn.d.Agricultural odorants, acetic acid, propanoic acid, 2-methylpropanoicacid, butanoic acid, 3-methylbutanoic acid, pentanoic acid, 4-methylpentanoic acid, hexanoic acid, heptanoic acid, phenol, 4-methylphenol, 4-ethylphenol, indole, 3-methylindole, Volatile fatty acid, phenol, 4-methylphenol, 4-ethylphenol, indole, and 3-methylindoleGC
MS

[32] Van Harreveld, 2003Nalophan20TobaccoDO
Cali-5-Bond coated Nalophan131

[33] Van Durme and Werbrouck, 2015Nalophan20 μmJapanese Indoor Air Standard mixGC
MS

[34] Wang et al., 2011Nalophan40 (gas)QCM sensors
Nalophan-125

[35] Zarra et al., 2012Nalophan25WWTP odorantsDO
Tedlar50
Teflon50

[36] Zhu et al., 2015Tedlarn.d.Ethylmercaptan, butyric acid, isovaleric acid, p-cresolGC
MS
Metallized-FEPn.d.

GC gas chromatography, MS mass spectrometry, PEA Polyester aluminium, WWTP waste water treatment plant, DO dynamic olfactometry, HPLC liquid chromatography, QCM quartz-crystal-microbalance.