Review Article

Refining Vegetable Oils: Chemical and Physical Refining

Table 1

Undesirable constituents in oil removed during refining.

ComponentOriginEffect

Free fatty acidsHydrolysis of triglycerides(i) Taste, smoke if heating
(ii) Hydrolysis

Phosphatides (phospholipids)Natural compounds(i) Cloudy aspect
(ii) Deposit a residue in the oil flavors
(iii) Dark color if heating

Oxidation productsOxidation of unsaturated fatty acids(i) Undesirable flavors
(ii) Stability
(iii) Color—nutrition

FlavorsNatural compounds of seeds, autooxidation(i) Odorous components
(ii) Flavors

Waxes and pigmentsNatural components of seeds(i) Odorous components
(ii) Flavors

Metals (iron and copper)Technological pollution
Pollution during storage transport and processing
(i) Oxidation catalysts
(ii) Stability
Chemical pollutants(i) Safety toxicity
Heavy metals
Pesticides
PAHs (B[a]P)
Mycotoxins
Dioxins