Synthesis and Characterization of a Linear [Mn₃(O₂CMe)₄(py)₈]²⁺ Complex

Table 2

Selected interatomic distances (Å) and angles for complex 1.

Bond Distances (Å)
	Mn1⋯Mn2			3.799(2)
	Mn1–O1			2.154(2)
	Mn1–O3			2.196(2)
	Mn1–N1			2.247(2)
	Mn2–O2			2.093(2)
	Mn2–O3			2.234(2)
	Mn2–N3			2.235(2)
	Mn2–O4			2.276(2)
	Mn2–N2			2.288(2)
	Mn2–N4			2.295(2)
Bond Angles (∘)
O1–Mn1–O1		180.0	O2–Mn2–O3		103.82(7)
O1–Mn1–O3		90.90(7)	O2–Mn2–N3		108.98(7)
O1′–Mn1–O3		89.10(7)	O3–Mn2–N3		146.90(7)
O3–Mn1–O3′		180.0	N3–Mn2–O4		89.50(7)
O1–Mn1–N1		90.57(7)	O2–Mn2–N2		90.28(8)
O1′–Mn1–N1		89.43(7)	O3–Mn2–N2		96.50(7)
O3–Mn1–N1		87.20(7)	N3–Mn2–N2		87.73(8)
O3′–Mn1–N1		92.80(7)	O4–Mn2–N2		86.28(7)
O1–Mn1–N1		90.57(7)	O3–Mn2–N4		89.30(7)
N1–Mn1–N1′		180.0(2)	N2–Mn2–N4		173.85(8)
			Mn1–O3–Mn2		118.07(7)