Journal of Atomic, Molecular, and Optical Physics
Volume 2011 (2011), Article ID 637593, 6 pages
Ultrafast Dynamics of 1,3-Cyclohexadiene in Highly Excited States
1Department of Chemistry, Brown University, Providence, RI 02912, USA
2LCLS Laser Department, SLAC National Accelerator Laboratory, Menlo Park, CA 94025, USA
3Department of Chemistry, Massachusetts Institute of Technology, Cambridge, MA 02139, USA
Received 2 March 2011; Revised 11 May 2011; Accepted 15 June 2011
Academic Editor: Geraldo M. Sigaud
Copyright © 2011 Christine C. Bühler et al. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.
- M. Klessinger and J. Michl, Excited States and Photochemistry of Organic Molecules, VCH, New York, NY, USA, 1995.
- D. Feldman, F. H. Glorieux, and J. W. Pikre, Eds., Vitamin D, Academic Press, San Diego, Calif, USA, 1997.
- M. Merchán, L. Serrano-Andrés, L. S. Slater, B. O. Roos, R. McDiarmid, and X. Xing, “Electronic spectra of 1,4-cyclohexadiene and 1,3-cyclohexadiene: a combined experimental and theoretical investigation,” Journal of Physical Chemistry A, vol. 103, no. 28, pp. 5468–5476, 1999.
- M. Garavelli, C. S. Page, P. Celani et al., “Reaction path of a sub-200 fs photochemical electrocyclic reaction,” Journal of Physical Chemistry A, vol. 105, no. 18, pp. 4458–4469, 2001.
- K. Kosma, S. A. Trushin, W. Fuß, and W. E. Schmid, “Cyclohexadiene ring opening observed with 13 fs resolution: coherent oscillations confirm the reaction path,” Physical Chemistry Chemical Physics, vol. 11, no. 1, pp. 172–181, 2009.
- S. Deb and P. M. Weber, “The ultrafast pathway of photon-induced electrocyclic ring-opening reactions: the case of 1,3-cyclohexadiene,” Annual Review of Physical Chemistry, vol. 62, pp. 19–39, 2011.
- N. Kuthirummal, F. M. Rudakov, C. L. Evans, and P. M. Weber, “Spectroscopy and femtosecond dynamics of the ring opening reaction of 1,3-cyclohexadiene,” Journal of Chemical Physics, vol. 125, Article ID 133307, 8 pages, 2006.
- J. B. Schönborn, J. Sielk, and B. Hartke, “Photochemical ring-opening of cyclohexadiene: quantum wavepacket dynamics on a global Ab Initio potential energy surface,” Journal of Physical Chemistry A, vol. 114, no. 12, pp. 4036–4044, 2010.
- W. Fuß, W. E. Schmid, and S. A. Trushin, “Time-resolved dissociative intense-laser field ionization for probing dynamics: femtosecond photochemical ring opening of 1,3-cyclohexadiene,” Journal of Chemical Physics, vol. 112, no. 19, pp. 8347–8362, 2000.
- X. Liang, M. G. Levy, S. Deb, J. D. Geiser, R. M. Stratt, and P. M. Weber, “Electron diffraction with bound electrons: the structure sensitivity of Rydberg Fingerprint Spectroscopy,” Journal of Molecular Structure, vol. 978, no. 1–3, pp. 250–256, 2010.
- A. M. Lindenberg, I. Kang, S. L. Johnson et al., “Time-resolved X-ray diffraction from coherent phonons during a laser-induced phase transition,” Physical Review Letters, vol. 84, no. 1, pp. 111–114, 2000.
- R. C. Dudek and P. M. Weber, “Ultrafast diffraction imaging of the electrocyclic ring-opening reaction of 1,3-cyclohexadiene,” Journal of Physical Chemistry A, vol. 105, no. 17, pp. 4169–4171, 2001.
- H. Ihee, V. A. Lobastov, U. M. Gomez et al., “Direct imaging of transient molecular structures with ultrafast diffraction,” Science, vol. 291, no. 5503, pp. 458–462, 2001.
- J. D. Cardoza, R. C. Dudek, R. J. Mawhorter, and P. M. Weber, “Centering of ultrafast time-resolved pump-probe electron diffraction patterns,” Chemical Physics, vol. 299, no. 2-3, pp. 307–312, 2004.
- N. Kuthirummal and P. M. Weber, “Rydberg states: sensitive probes of molecular structure,” Chemical Physics Letters, vol. 378, no. 5-6, pp. 647–653, 2003.
- W. Cheng, N. Kuthirummal, J. L. Gosselin, T. I. Sølling, R. Weinkauf, and P. M. Weber, “Control of local ionization and charge transfer in the bifunctional molecule 2-phenylethyl-N,N-dimethylamine using rydberg fingerprint spectroscopy,” Journal of Physical Chemistry A, vol. 109, no. 9, pp. 1920–1925, 2005.
- J. L. Gosselin and P. M. Weber, “Rydberg fingerprint spectroscopy: a new spectroscopic tool with local and global structural sensitivity,” Journal of Physical Chemistry A, vol. 109, no. 22, pp. 4899–4904, 2005.
- N. Kuthirummal and P. M. Weber, “Structure sensitive photoionization via Rydberg levels,” Journal of Molecular Structure, vol. 787, no. 1–3, pp. 163–166, 2006.
- J. D. Cardoza, F. M. Rudakov, N. Hansen, and P. M. Weber, “Identification of isomeric hydrocarbons by Rydberg photoelectron spectroscopy,” Journal of Electron Spectroscopy and Related Phenomena, vol. 165, no. 1–3, pp. 5–10, 2008.
- M. P. Minitti, J. L. Gosselin, T. I. Sølling, and P. M. Weber, “The ultrafast photofragmentation pathway of N,N-dimethylisopropylamine,” in FemtoChemistry VII, M. L. Kimble, Ed., Elsevier, New York, NY, USA, 2006.
- J. L. Gosselin, M. P. Minitti, F. M. Rudakov, T. I. Sølling, and P. M. Weber, “Energy flow and fragmentation dynamics of N,N-dimethylisopropylamine,” Journal of Physical Chemistry A, vol. 110, no. 12, pp. 4251–4255, 2006.
- N. Kuthirummal and P. M. Weber, “Probing reaction dynamics with Rydberg states: the ring opening reaction of 1,3-cyclohexadiene,” in Femtochemistry and Femtobiology: Ultrafast Events in Molecular Science, M. Martin and J. T. Hynes, Eds., Elsevier, New York, NY, USA, 2004.
- Y. Liu, J. Lin, G. Huang, Y. Guo, and C. Duan, “Simple empirical analytical approximation to the Voigt profile,” Journal of the Optical Society of America B, vol. 18, no. 5, pp. 666–672, 2001.
- F. Rudakov and P. M. Weber, “Ground state recovery and molecular structure upon ultrafast transition through conical intersections in cyclic dienes,” Chemical Physics Letters, vol. 470, no. 4–6, pp. 187–190, 2009.
- J. Bao and P. M. Weber, “Ultrafast dynamics of highly excited trans-stilbene: a different twist,” Journal of Physical Chemistry Letters, vol. 1, no. 1, pp. 224–227, 2010.
- J. D. Cardoza, F. M. Rudakov, and P. M. Weber, “Electronic spectroscopy and ultrafast energy relaxation pathways in the lowest rydberg states of trimethylamine,” Journal of Physical Chemistry A, vol. 112, no. 43, pp. 10736–10743, 2008.
- B. Kim, N. Thantu, and P. M. Weber, “High resolution photoelectron spectroscopy: the vibrational spectrum of the 2-aminopyridine cation,” The Journal of Chemical Physics, vol. 97, no. 8, pp. 5384–5391, 1992.
- M. P. Minitti, J. D. Cardoza, and P. M. Weber, “Rydberg fingerprint spectroscopy of hot molecules: structural dispersion in flexible hydrocarbons,” Journal of Physical Chemistry A, vol. 110, no. 34, pp. 10212–10218, 2006.
- C. P. Schick, S. D. Carpenter, and P. M. Weber, “Femtosecond multiphoton ionization photoelectron spectroscopy of the S2 state of phenol,” Journal of Physical Chemistry A, vol. 103, no. 49, pp. 10470–10476, 1999.