Journal of Thermodynamics

Research Article

Supercritical Phase Equilibria Modeling of Glyceride Mixtures and Carbon Dioxide Using the Group Contribution EoS

Table 1

Experimental VLE data and standard deviations obtained in the regression of the alcohol-ester binary group interaction parameters.


Binary mixture	Data range			^a	^b	^b	Ref.
Binary mixture	(K)	(bar)		^a	^b	^b	Ref.

1-propanol + methyl propanoate	328–348	0.2–0.8	45		8.10	7.98	[24]
1-butanol + methyl propanoate	348	0.2–0.9	20		21.51	18.36	[25]
ethanol + methyl propanoate	345–352	1.01	33	3.37	6.52		[26]
1-propanol + methyl propanoate	352–367	1.01	37	3.64	5.00		[26]
1-butanol + methyl propanoate	342–390	1.3–0.8	118		13.53	11.44	[26]
1-butanol + ethylacetate	348–387	0.96	20		13.92	9.56	[27]
ethanol + methyl acetate	330–351	1.01	30		9.16	11.99	[28]
1-propanol + methyl acetate	330–370	1.01	38		10.16	9.01	[28]
ethanol + ethylacetate	345–350	1.01	60	13.21	12.50		[29]

^a.
^b.