Polycations XX: New Monodentate Cationic Ligands and Their Coordination with Ruthenium for the Construction of Complexes Expressing Enhanced Interaction with DNA

<table class="table-group" id="tab1"><tr><td><table class="table"><tr><td class="thead-hr" colspan="3"><hr/></td></tr><tr class="thead"><td align="left">Compound</td><td align="center"><span style="width: 34.6875px;"><svg height="16.450001" id="M14" style="vertical-align:-3.3907pt" version="1.1" viewbox="0 0 34.6875 16.450001" width="34.6875" xmlns="http://www.w3.org/2000/svg" xmlns:xlink="http://www.w3.org/1999/xlink">
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<g transform="matrix(.012,0,0,-.012,9.45,16.25)"><path d="M797 0h-214v26q46 5 58 17.5t12 63.5v167q0 116 -88 116q-48 0 -112 -52q3 -18 3 -42v-195q0 -46 11 -58t53 -17v-26h-214v26q48 5 59.5 17t11.5 60v172q0 115 -88 115q-47 0 -109 -52v-235q0 -47 10 -59.5t48 -17.5v-26h-211v26q50 5 62.5 17t12.5 60v207q0 48 -9 59.5
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<g transform="matrix(.017,0,0,-.017,.062,7.675)"><path d="M387 375q0 -16 -17 -31t-29 -15q-9 0 -12 13q-13 74 -80 74q-36 0 -61 -24.5t-25 -56.5t24 -51.5t68 -19.5q33 0 47 2l2 -7l-32 -42q-20 2 -54 2q-45 0 -74 -21.5t-29 -60.5q0 -41 28 -65.5t73 -24.5q78 0 145 67l17 -23q-33 -47 -84.5 -75t-111.5 -28q-70 0 -114.5 35.5
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</svg> (<svg height="8.5" id="M16" style="vertical-align:-0.0pt" version="1.1" viewbox="0 0 10.1 8.5" width="10.1" xmlns="http://www.w3.org/2000/svg" xmlns:xlink="http://www.w3.org/1999/xlink">
<g transform="matrix(.017,0,0,-.017,.062,8.438)"><path d="M528 54l-36 -38l-198 201l-198 -201l-36 38l197 200l-197 201l36 38l198 -202l198 202l36 -38l-197 -201z" id="xD7"></path></g>
</svg>10<sup>4</sup>)</td></tr><tr><td class="thead-hr" colspan="3"><hr/></td></tr><tr><td align="left"> </td><td align="center">254</td><td align="center">6.7</td></tr><tr><td align="left"><b>16</b></td><td align="center">288</td><td align="center">8.7</td></tr><tr><td align="left"> </td><td align="center">463</td><td align="center">2.3</td></tr><tr><td align="left" colspan="3"><hr/></td></tr><tr><td align="left"> </td><td align="center">249</td><td align="center">12</td></tr><tr><td align="left"><b>17</b></td><td align="center">286</td><td align="center">13</td></tr><tr><td align="left"> </td><td align="center">464</td><td align="center">2.4</td></tr><tr><td align="left" colspan="3"><hr/></td></tr><tr><td align="left"> </td><td align="center">253</td><td align="center">11.</td></tr><tr><td align="left"><b>18</b></td><td align="center">288</td><td align="center">13.</td></tr><tr><td align="left"> </td><td align="center">465</td><td align="center">3.5</td></tr><tr><td align="left" colspan="3"><hr/></td></tr><tr><td align="left"> </td><td align="center">252</td><td align="center">5.7</td></tr><tr><td align="left"><b>20</b></td><td align="center">286</td><td align="center">6.0</td></tr><tr><td align="left"> </td><td align="center">475</td><td align="center">1.6</td></tr><tr><td align="left" colspan="3"><hr/></td></tr><tr><td align="left"> </td><td align="center">245</td><td align="center">4.2</td></tr><tr><td align="left" rowspan="2"><b>21</b></td><td align="center">291</td><td align="center">10.</td></tr><tr><td align="center">348</td><td align="center">1.8</td></tr><tr><td align="left"> </td><td align="center">478</td><td align="center">1.6</td></tr><tr><td align="left" colspan="3"><hr/></td></tr><tr><td align="left"> </td><td align="center">249</td><td align="center">4.1</td></tr><tr><td align="left" rowspan="2"><b>22</b></td><td align="center">290</td><td align="center">8.7</td></tr><tr><td align="center">344</td><td align="center">1.6</td></tr><tr><td align="left"> </td><td align="center">471</td><td align="center">1.6</td></tr><tr class="table-tr"><td colspan="3"><hr class="tbody-hr"/></td></tr></table></td></tr></table>

Absorption maxima and relative intensities for UV-visible spectra of selected new ruthenium complexes bearing cationic ligands.

Organic Chemistry International

tab1

Table 1

Table 1: Polycations XX: New Monodentate Cationic Ligands and Their Coordination with Ruthenium for the Construction of Complexes Expressing Enhanced Interaction with DNA 

Table 1 | Polycations XX: New Monodentate Cationic Ligands and Their Coordination with Ruthenium for the Construction of Complexes Expressing Enhanced Interaction with DNA 