Synthesis and Studies on S-Triazine-Based Ligand and Its Metal Complexes

<table class="table-group" id="tab5"><tr><td><table class="table"><tr><td class="thead-hr" colspan="3"><hr/></td></tr><tr class="thead"><td align="left">Compound</td><td align="center">Excitation wavelength  <br/><svg height="15.65" id="M76" style="vertical-align:-3.39069pt" version="1.1" viewbox="0 0 27.950001 15.65" width="27.950001" xmlns="http://www.w3.org/2000/svg" xmlns:xlink="http://www.w3.org/1999/xlink">
<g transform="matrix(.017,-0,0,-.017,.062,11.362)"><path d="M671 0h-247v28q49 7 60 18.5t0 45.5l-155 438h-2q-21 -61 -74 -204.5t-75 -210.5q-15 -51 -4.5 -65t67.5 -22v-28h-221v28q50 9 69 26.5t45 84.5l202 517l32 9l194 -535q23 -61 42 -78.5t67 -23.5v-28z" id="x39B"></path></g>
<g transform="matrix(.012,-0,0,-.012,11.725,15.45)"><path d="M433 39l-85 -51q-27 0 -47 20q-16 16 -24 44q-5 -3 -24 -16.5t-27 -18.5t-23 -13.5t-25 -12t-19 -3.5q-52 0 -86 36.5t-34 85.5q0 71 81 99q128 43 155 65v17q0 54 -23 83.5t-62 29.5q-28 0 -45 -19t-29 -66q-7 -23 -29 -23q-15 0 -29 13t-14 30t31 40q25 19 68.5 40.5
t81.5 29.5q49 0 82 -27q45 -39 45 -123v-185q0 -60 35 -60q18 0 36 11zM275 84v156q-12 -6 -49 -23t-41 -19q-31 -14 -46 -31t-15 -43q0 -35 22.5 -55.5t48.5 -20.5q19 0 42 10.5t38 25.5z" id="x61"></path></g><g transform="matrix(.012,-0,0,-.012,16.853,15.45)"><path d="M152 404l81 35q23 10 41 10q81 0 139 -61.5t58 -149.5q0 -107 -74.5 -178.5t-176.5 -71.5q-71 0 -147 36v555q0 48 -9.5 59.5t-56.5 15.5v23q79 10 145 35v-308zM152 374v-258q0 -20 6 -35q7 -19 30 -37t58 -18q63 0 99.5 50t36.5 137q0 82 -43.5 131t-108.5 49
q-44 0 -78 -19z" id="x62"></path></g><g transform="matrix(.012,-0,0,-.012,22.898,15.45)"><path d="M319 325l-25 -7q-33 99 -103 99q-29 0 -47 -19.5t-18 -49.5t22 -49.5t62 -36.5q63 -26 95 -57t32 -79q0 -64 -50 -101t-115 -37q-35 0 -67.5 10.5t-46.5 23.5q-5 11 -11 51t-6 67l27 5q14 -53 46.5 -88.5t75.5 -35.5q29 0 50 19.5t21 50.5t-19.5 51.5t-59.5 39.5
q-28 12 -46 22.5t-38.5 27t-30.5 38.5t-10 49q0 54 42.5 92t109.5 38q48 0 88 -18q6 -15 13 -50.5t9 -55.5z" id="x73"></path></g>
</svg>  (nm)</td><td align="center">Fluorescence wavelength <br/>  <svg height="15.65" id="M77" style="vertical-align:-3.39069pt" version="1.1" viewbox="0 0 30.4 15.65" width="30.4" xmlns="http://www.w3.org/2000/svg" xmlns:xlink="http://www.w3.org/1999/xlink">
<g transform="matrix(.017,-0,0,-.017,.062,11.362)"><path d="M671 0h-247v28q49 7 60 18.5t0 45.5l-155 438h-2q-21 -61 -74 -204.5t-75 -210.5q-15 -51 -4.5 -65t67.5 -22v-28h-221v28q50 9 69 26.5t45 84.5l202 517l32 9l194 -535q23 -61 42 -78.5t67 -23.5v-28z" id="x39B"></path></g>
<g transform="matrix(.012,-0,0,-.012,11.725,15.45)"><path d="M380 106l15 -22q-42 -52 -87 -74t-76 -22q-89 0 -142 62t-53 151q0 103 66 175q67 73 146 73h1q61 0 105.5 -46.5t44.5 -105.5q0 -16 -4.5 -22.5t-18.5 -9.5q-54 -10 -262 -17q1 -95 46 -143.5t104 -48.5q61 0 115 50zM225 412q-35 0 -64.5 -32.5t-40.5 -90.5q83 0 170 3
q14 0 19 4.5t5 15.5q1 41 -23.5 70.5t-65.5 29.5z" id="x65"></path></g><g transform="matrix(.012,-0,0,-.012,16.782,15.45)"><path d="M797 0h-214v26q46 5 58 17.5t12 63.5v167q0 116 -88 116q-48 0 -112 -52q3 -18 3 -42v-195q0 -46 11 -58t53 -17v-26h-214v26q48 5 59.5 17t11.5 60v172q0 115 -88 115q-47 0 -109 -52v-235q0 -47 10 -59.5t48 -17.5v-26h-211v26q50 5 62.5 17t12.5 60v207q0 48 -9 59.5
t-52 18.5v23q79 14 139 41v-81q3 2 29 20.5t44 29.5q45 28 81 28t66 -22t46 -61q25 20 83 57q39 26 76 26q59 0 93 -40t34 -113v-193q0 -49 10.5 -60.5t54.5 -16.5v-26z" id="x6D"></path></g><g transform="matrix(.012,-0,0,-.012,26.527,15.45)"><path d="M135 536q-20 0 -35 15.5t-15 35.5q0 22 15 37t36 15t35.5 -15t14.5 -37q0 -21 -15 -36t-36 -15zM252 0h-220v26q48 5 59 17t11 63v206q0 47 -9 58t-54 18v24q78 12 142 39v-345q0 -51 11.5 -63t59.5 -17v-26z" id="x69"></path></g>
</svg>  (nm)</td></tr><tr><td class="thead-hr" colspan="3"><hr/></td></tr><tr><td align="left">BMTDT</td><td align="center">455</td><td align="center">522</td></tr><tr><td align="left">Cu(BMTDT)Cl<sub>2</sub></td><td align="center">657</td><td align="center">681</td></tr><tr><td align="left">Ni(BMTDT)Cl<sub>2</sub></td><td align="center">496</td><td align="center">580</td></tr><tr><td align="left">Co(BMTDT)Cl<sub>2</sub></td><td align="center">609</td><td align="center">679</td></tr><tr class="table-tr"><td colspan="3"><hr class="tbody-hr"/></td></tr></table></td></tr></table>

Fluorescence parameters of ligand and its metal(II) complexes.

International Journal of Inorganic Chemistry

tab5

Table 5

Table 5: Synthesis and Studies on S-Triazine-Based Ligand and Its Metal Complexes 