Aqueous Photo-Living Radical Polymerization of Sodium Methacrylate Using a Water-Soluble Nitroxide Mediator

<table class="table-group" id="tab2"><tr><td><table class="table"><tr><td class="thead-hr" colspan="5"><hr/></td></tr><tr class="thead"><td align="left">  V-80 (mM)</td><td align="center">Time (h)</td><td align="center">Conversion (%)</td><td align="center"><i>Mn </i><sup>
									a</sup></td><td align="center"><i>Mw/Mn </i><sup>
									a</sup></td></tr><tr><td class="thead-hr" colspan="5"><hr/></td></tr><tr><td align="left">14.9</td><td align="center"> 3.5</td><td align="center">71</td><td align="center">86,700</td><td align="center">2.22</td></tr><tr><td align="left">22.5</td><td align="center"> 5</td><td align="center">76</td><td align="center">75,800</td><td align="center">2.16</td></tr><tr><td align="left">44.8</td><td align="center"> 9</td><td align="center">78</td><td align="center">60,400</td><td align="center">2.05</td></tr><tr class="table-tr"><td colspan="5"><hr class="tbody-hr"/></td></tr></table></td></tr><tr class="table-fn"><td>[NaMA]<sub>0</sub> = 9.25 mM, HTEMPO/V-80 = 1.06, FS/HTEMPO = 0.53.<br/><sup>
								a</sup>Estimated by GPC based on PNaMA standards.<br/></td></tr></table>

The HTEMPO-mediated polymerization of NaMA by V-80.

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Table 2: Aqueous Photo-Living Radical Polymerization of Sodium Methacrylate Using a Water-Soluble Nitroxide Mediator 