International Journal of Inorganic Chemistry

Research Article

Synthesis and Crystal Structure of

Table 1

Crystal data and parameters for data collection for [MnIII(5-Br-salpn)(DMF)2][B(C6H5)4].
Empirical formulaC47H48BBr2MnN4O4
Formula weight958.46
Temperature100(2) K
Wavelength1.54178 
Crystal systemmonoclinic
Space groupP21/c
Unit cell dimensionsa = 12.3798(1) Å α = 90°
 b = 12.6099(1) Å  = 102.013(1)°
  = 28.9438(3) Å  = 90°
Volume 4419.41(7) Å3
Z 4
Density (calculated)1.441 mg/m3
Absorption coefficient4.924 mm−1
F(000)1960
Crystal size0.48 × 0.22 × 0.08 mm
range for data collection3.12–67.31°
Limiting indices−14 < h < 14, –15 < k < 15, −34 < l < 33
Reflections collected36039
Independent reflections7606
Absorption correctionSADABS
Refinement methodfull-matrix least-squares on
Data/restraints/
parameters		7606/0/537
Goodness-of-fit on 1.096
Final indices [ σ(I)] = 0.0610, = 0.0240
indices (all data) = 0.0615, = 0.0248

, where .