Research Article
Crystal Structures and Magnetic Properties of Two New Cobalt(II) Complexes with Triazole-Substituted Nitronyl and Imino Nitroxide Radicals
Table 1
Crystal data and structure refinement for complex 1 and complex 2.
| | Complex 1 | Complex 2 |
| Formula | C25 H22 F12 Co N5 O6 | C25 H22 F12 Co N5 O5 | Formula weight | 775.11 | 759.106 | Crystal system | Triclinic | Triclinic | Space group | | | Unit cell dimensions (, °) | | | a | 10.208(2) | 10.107(2) | b | 11.678(9) | 10.983(2) | c | 14.680(3) | 15.168(3) | | 79.02(3) | 86.19(3) | | 76.53(3) | 76.17(3) | | 67.98(3) | 77.53(3) | Volume (), Z | 1567.4(5), 2 | 1596.2(5), 1 | F(000) | 1160 | 748 | range for data collection (°) | 1.89 to 28.37 | 1.90 to 28.37 | Limiting indices |
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| Reflections collected | 37545 | 28519 | Independent reflections | 7808 | 7899 () | Completeness (%) | 99.3 | 98.7 | Goodness-of-fit on | 1.097 | 1.515 | Final R indices (I 2 (I)) | ; | ; | R indices (all data) | ; | ; |
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