Research Article
Crystal Structures and Magnetic Properties of Two New Cobalt(II) Complexes with Triazole-Substituted Nitronyl and Imino Nitroxide Radicals
Table 2
Selected bond distances (
) and angles (°) for complex
1 and complex
2.
| | Complex 1 | | | | | Co(1)–O(1) | 2.025(3) | Co(1)–O(6) | 2.031(2) | | Co(1)–O(4) | 2.030(3) | Co(1)–O(5) | 2.054(2) | | Co(1)–O(3) | 2.057(2) | Co(1)–N(3) | 2.251(2) | | N(1)–O(1) | 1.289(3) | N(2)–O(2) | 1.265(4) | | O(1)–Co(1)–O(6) | 89.30(10) | O(1)–Co(1)–O(4) | 177.82(10) | | O(6)–Co(1)–O(4) | 91.26(10) | O(1)–Co(1)–O(5) | 86.09(11) | | O(6)–Co(1)–O(3) | 175.71(8) | O(5)–Co(1)–O(3) | 167.92(10) | | Complex 2 | | | | | Co(2)–O(5) | 2.028(2) | Co(2)–O(3) | 2.045(2) | | Co(2)–O(2) | 2.044(2) | Co(2)–O(4) | 2.069(2) | | Co(2)–N(1) | 2.088(2) | Co(2)–N(5) | 2.287(2) | | N(2)–O(1) | 1.275(3) | | | | O(5)–Co(2)–O(3) | 89.69(9) | O(5)–Co(2)–O(2) | 174.56(7) | | O(4)–Co(2)–N(5) | 173.43(9) | O(3)–Co(2)–N(1) | 170.37(9) | | O(3)–Co(2)–O(4) | 87.28(11) | N(1)–Co(2)–N(5) | 77.07(9) |
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