Research Article

Gasification Coupled Chemical Looping Combustion of Coal: A Thermodynamic Process Design Study

Table 3

Comparison of net energy obtainable from direct combustion and gasification coupled CLC of coal.

CaseC3C1C5B5B3B2C2B1C4B4

HCCT (°C)650500700750700650600600650700
Air required (moles)3.763.763.763.763.763.763.763.763.763.76
Preheating of coal (kJ)10.067.0911.1112.1911.1110.069.049.0410.0611.11
Energy to heat air (kJ)90.2067.6997.80105.4597.8090.2082.6582.6590.2597.80
Reaction enthalpy from direct combustion (kJ)−394.44−394.11−394.54−394.65−394.54−394.44−394.33−394.33−394.44−394.54
Energy to cool N2 (kJ)−69.95−52.60−75.81−81.71−75.81−69.95−64.13−64.13−69.95−75.81
Energy to cool CO2 (kJ)−29.56−21.78−32.22−34.91−32.22−29.56−26.93−26.93−29.56−32.22
Net energy from direct combustion (kJ)−393.68−393.71−393.66−393.63−393.66−393.68−393.69−393.69−393.68−393.66
Net energy from gasification coupled CLC process (kJ)−390.16 −389.07−388.46−388.43−388.35−388.34−388.24−388.17−388.16−388.02

Energy Difference(kJ) 3.52 4.64 5.20 5.20 5.31 5.34 5.46 5.53 5.52 5.64