|
Sl. no. | Materials | Synthesis method | Properties/uses | Average size of Core-shell particle | References |
|
1 | Carbon black/polypyrrole | In situ chemical oxidative polymerization | Electrochemical energy storage | 50–100 nm | [13] |
|
2 | BaTiO3/PMMA | In situ atom transfer radical polymerization (ARTP) | High dielectric constant materials with the inherent low loss of the base polymer | 150–200 nm | [14] |
|
3 | Polystyrene-n-butyl acrylate-methy methacrylate@silica | Emulsion polymerization | Dynamic modulus | 30–80 nm | [15] |
|
4 | Poly(vinyl amine)-silica | Wet chemical route | Silica precursor for composite materials formation | 200–250 nm | [16] |
|
5 | Silica@PMMA brush | Surface initiated photopolymerization | PMMA composite with enhanced thermal and mechanical properties | 100–150 nm | [17] |
|
6 | CdS@PMMA | Different physical and chemical routes | Electrical transport properties | 10–200 nm | [18] |
|
7 | Spiropyran-silica
| Two-step sol-gel synthesis | Photochromic properties | 100–150 nm | [19] |
|
8 | (MMA@CuO) | Solution deposition method | — | 20–30 nm | [20] |
|
9 | Well-defined oxide (SiO2) core-polymer (PMMA) shell | Chemical route | High mechanical strength | 20–90 nm
| [21] |
|
10 | T-ZnO whiskers/Polyaniline | Graft polymerization | Electrical conductivity | 500 nm | [22] |
|
11 | PS cores and thermosensitive poly(N-isopropylacrylamide) (PNIPA) shells | Self-assembly encapsulation | Drug diffusion | Less than 100 nm | [23] |
|
12 | Silica-polymer (methyl methacrylate (MMA)) core-shell nanoparticles | Seed copolymerization | Excellent antimicrobial | 20–30 nm | [24] |
|
13 | PMMA@PCL | Coaxial electrospraying | — | 3–6 µm | [25] |
|
14 | PS@SiO2 | Sol-gel synthesis | — | 200–250 nm | [26] |
|
15 | Fe3O4@styrene/butyl acrylate | Initiator free miniemulsion polymerization | Magnetite and their corresponding behavior | 150–200 nm | [27] |
|
16 | Polyaniline-polystyrene sulfonate@Fe3O4 | Surface-initiated polymerization | Conductive and magnetic properties | 60–200 nm | [28] |
|
17 | SiO2@polypyrrole | In situ polymerization through electrostatic interaction | — | 200–300 nm | [29] |
|
18 | PMMA spheres with a core of Fe3O4 | Spontaneous Pickering emulsification | — | 50–80 nm | [30] |
|
19 | PS@SiO2 | Alcaholic dispersion polymerization | Catalytic | 1000 nm | [31] |
|
20 | Poly(2-vinylpyridine) @silica | Emulsion polymerization | Cationic azo initiator | 200 nm | [32] |
|
21 | SiO2@Poly(3-aminophenylboronic acid) (PABBA) | Ultrasonic irradiation method | Conductivity | 100–200 nm | [33] |
|
22 | Collagen-g-PMMA Ag@TiO2 Collagen-g-PMMA@TiO2 | Graft polymerization water in oil emulsion polymerization ultrasonic irradiation | Lower infrared emissivity | 60–100 nm | [34] |
|
23 | SiO2@polyaniline | In situ polymerization | High electrical conductivity | 20–30 nm | [35] |
|
24 | PANI@Fe3O4 | Ultrasonic polymerization to assist chemical oxidative polymerization | Decreases its electrical conductivity | 20–25 nm | [36] |
|
25 | @PAM PAM: polyacrylamide | UV assisted in situ surface initiated free radical polymerization | Good dispersion stability | 50–200 nm | [37] |
|
26 | Au-impregnated polyacrylonitrile (PAN)/polythiophene (PTH) core-shell nanofibers | Shadow mask | High-performance semiconducting properties | 30–50 nm | [38] |
|
27 | Smart core-shell hybrid nanogels with Ag nanoparticle core and poly(N-isopropylacrylamide- co-acrylic acid) shell | Copolymerization process | pH-Regulated drug delivery and for cancer cell imaging | 40–80 nm | [39] |
|
28 | PS cores and Au shell nanoparticle coronae | Self-assembly | Hydrophobic nanoparticles | 80 nm | [40] |
|
29 | Upconverting NaYF4 nanoparticles with PEG-phosphate ligands | Water-dispersible | Biolabeling within the biological window | 30–40 nm | [41] |
|
30 | Au@PEG (polyethylene glycol) | Combined swelling heteroaggregation | Dielectric applications | 300 nm | [42] |
|
31 | Ag-polystyrene | Hydrothermal method | Characteristic plasmon resonance | 200 nm | [43] |
|
32 | Ag@poly(acrylic acid)
| In situ immobilization | Tunable photoluminescence, act as multiple-sensitive hybrid microgels | 100 nm | [44] |
|
33 | Highly controlled core (Au/shell (PANI) structures
| In situ polymerization,
| Tunable conductive polymer | 61–92 nm | [45] |
|
34 | Au-PS hybrid colloidal particles | Precipitation polymerization method | Fabricating photonic devices via a self-assembly approach | 200–250 nm | [46] |
|
35 | Fe3O4@polyaniline@Au Nanocomposites | Solvothermal reaction | Catalytic activity | 70–80 nm | [47] |
|
36 | Luminescent silver@phenol formaldehyde resin core-hell nanospheres | Facile one-step hydrothermal approach | In vivo bioimaging
| 180–1000 nm | [48] |
|
37 | Poly(butylene adipate) on the surface of SiO2 | Chemical route | Improve the toughness and stiffness | 100–1000 nm | [49] |
|
38 | Polyaniline-coated poly(butyl methacrylate) | Chemical route | Printing technology | 100 nm | [50] |
|