Journal of Thermodynamics / 2013 / Article / Tab 4 / Research Article
Modified Lennard-Jones Potentials with a Reduced Temperature-Correction Parameter for Calculating Thermodynamic and Transport Properties: Noble Gases and Their Mixtures (He, Ne, Ar, Kr, and Xe) Table 4 Deviations between experimental and calculated thermal conductivities of pure noble gases.
Compound Number of points Average RMSDr in λ (%)
(K)
Reference Present study L-J Simsci Refprop 64 7.77 10.7 2.94 3.52 70–1000 [56 ] 8 2.61 5.16 0.78 1.03 298–1010 [31 ] 8 2.33 4.40 1.68 1.32 298–973 [34 ] 8 2.41 4.42 1.75 1.27 298–973 [36 ] 27 5.04 7.95 1.09 1.81 275–725 [57 ] 93 6.10 9.10 7.20 20.1 20–1000 [58 ] 8 2.47 4.67 1.30 0.95 298–973 [59 ] 4 10.2 13.5 4.98 4.16 303–363 [100 ] 2 7.72 11.2 2.35 1.25 303 [101 ] 25 3.66 6.21 1.41 4.52 50–973 [26 ] 6 4.01 6.76 1.19 1.91 100–600 [29 ] 11 4.95 7.65 1.44 1.95 100–600 [60 ] Helium 29 6.90 9.60 2.50 2.80 80–1000 [102 ] 102 6.80 9.50 4.70 12.5 20–1000 [103 ] 14 0.41 0.64 0.24 0.31 350–1000 [104 ] 6 7.94 11.0 3.37 3.18 303–589 [105 ] 52 5.90 8.60 5.50 17.4 20–1000 [106 ] 5 11.0 14.0 6.88 7.20 250–600 [62 ] 1 5.40 8.76 0.09 1.04 596 [107 ] 1 7.24 10.3 1.72 0.53 291 [108 ] 4 10.4 13.6 5.11 4.19 308–363 [109 ] 2 4.68 7.32 1.32 0.07 302–793 [110 ] 1 6.33 9.56 0.92 0.09 311 [111 ] 1 6.57 10.0 1.20 0.08 302 [112 ] 13 2.16 4.39 1.06 0.29 373–973 [63 ] Average 495* 5.90 8.59 3.94 9.47 8 1.52 0.62 1.07 2.91 298–973 [64 ] 8 2.50 1.16 0.66 3.87 298–973 [65 ] 1 1.04 0.54 1.10 2.53 291 [47 ] 8 2.74 1.41 0.66 4.11 298–973 [36 ] 29 3.50 2.53 0.94 4.11 90–1300 [56 ] 44 1.36 0.86 1.65 2.40 275–1275 [57 ] 111 2.83 2.65 5.95 12.7 27–1000 [58 ] 8 2.55 1.17 0.76 3.92 298–973 [59 ] 4 1.67 3.25 2.10 0.84 303–363 [100 ] 3 1.25 0.76 1.02 2.14 313–363 [113 ] Neon 22 2.40 1.70 2.40 4.36 50–973 [26 ] 6 1.81 1.34 1.09 3.25 100–600 [29 ] 11 1.48 3.03 2.50 2.04 100–600 [60 ] 15 2.92 1.63 0.53 4.01 273–1100 [102 ] 111 2.17 2.35 1.59 4.48 27–1500 [114 ] 24 2.92 1.41 1.01 5.94 350–1500 [104 ] 4 1.39 2.96 1.50 0.37 303–318 [105 ] 1 1.36 2.90 1.53 0.14 311 [115 ] 1 0.20 1.39 0.32 1.73 296 [107 ] 1 1.04 0.53 1.11 2.54 291 [108 ] 2 5.86 4.27 4.28 7.50 302–793 [110 ] Average 422* 2.41 2.08 2.63 6.20 21 2.09 2.72 1.07 1.00 202–394 [90 ] 3 2.15 3.97 0.48 5.08 90–273 [108 ] 1 1.75 2.95 4.90 4.23 1373 [116 ] 1 0.14 4.35 1.09 2.98 291 [47 ] 9 1.06 5.27 0.53 1.24 298–1124 [31 ] 8 1.21 5.11 0.49 1.17 298–973 [64 ] 8 1.53 5.71 0.66 0.99 298–973 [65 ] 8 1.48 5.66 0.77 1.09 298–973 [35 ] 66 1.76 4.50 1.25 1.60 90–2000 [56 ] 14 2.25 6.41 2.36 2.57 331–645 [117 ] 97 1.74 4.98 0.80 0.99 280–1390 [57 ] 122 2.55 6.17 1.26 5.23 87–3300 [58 ] 235 2.10 5.97 1.02 2.20 80–2000 [92 ] 63 2.74 3.09 3.08 5.05 90–500 [79 ] 63 3.82 4.80 3.40 3.53 90–500 [93 ] 8 1.36 5.50 0.54 1.10 298–973 [59 ] 3 0.77 4.70 1.37 2.70 313–363 [113 ] Argon 29 2.63 5.64 2.48 7.10 50–3273 [26 ] 6 1.92 4.11 2.46 5.20 100–600 [29 ] 11 1.65 3.37 1.39 3.07 100–600 [60 ] 54 2.02 5.78 1.07 2.55 80–2000 [102 ] 118 1.67 4.82 1.21 2.14 88–2500 [103 ] 24 1.70 6.20 0.50 0.90 350–1500 [104 ] 4 2.73 3.57 1.65 0.77 273–593 [105 ] 4 0.49 4.15 0.68 2.20 308–363 [118 ] 3 1.08 3.52 0.21 1.81 300–340 [119 ] 8 0.79 4.42 1.20 2.51 295–420 [120 ] 60 2.03 4.95 1.16 2.04 90–2000 [106 ] 7 1.41 3.86 1.09 1.43 250–1000 [62 ] 1 1.40 3.19 0.25 1.52 311 [115 ] 1 1.14 3.41 0.06 1.93 296 [107 ] 4 0.50 4.15 0.67 2.20 308–363 [109 ] 2 3.10 7.10 2.40 2.70 302–793 [110 ] 1 1.40 3.20 0.25 1.52 311 [111 ] 22 1.46 4.21 0.84 3.31 87–1000 [29 ] Average 1089* 2.11 5.22 1.31 2.82 Krypton 9 1.90 14.8 0.82 2.93 298–1149 [31 ] 8 1.80 14.8 0.88 3.10 298–973 [64 ] 8 1.65 15.1 1.24 3.44 298–973 [65 ] 18 3.20 19.5 4.18 6.57 125–1300 [56 ] 5 4.88 10.6 1.94 0.94 291–318 [57 ] 101 2.33 14.0 1.71 3.19 119–1900 [58 ] 6 3.12 13.4 2.25 3.45 100–600 [26 ] 235 2.60 15.5 2.50 4.50 80–2000 [92 ] 51 2.50 12.5 0.96 2.50 125–500 [93 ] 8 1.75 14.9 1.10 3.28 298–973 [59 ] 3 0.81 15.5 3.68 5.50 313–363 [113 ] 27 3.50 14.6 2.70 7.74 50–2273 [26 ] 10 4.62 10.8 2.46 0.64 150–600 [60 ] 109 5.80 14.4 5.33 6.25 120–2000 [114 ] 24 3.00 15.9 2.50 3.50 350–1500 [104 ] 5 5.76 9.80 2.67 0.78 303–318 [105 ] 4 4.24 11.3 1.35 1.06 308–363 [118 ] 1 4.38 11.0 1.30 0.65 311 [115 ] 1 4.16 10.9 1.17 0.81 291 [108 ] 4 4.21 11.3 1.34 1.11 308–363 [109 ] 2 4.06 17.4 5.03 6.98 302–793 [110 ] Average 639* 3.22 14.7 2.70 4.35 7 1.29 14.2 9.68 2.32 202–298 [90 ] 8 3.28 14.2 2.65 1.43 298–973 [35 ] 24 7.30 17.7 1.02 4.55 175–1300 [56 ] 1 3.53 12.7 0.60 1.95 291 [57 ] 1 3.36 12.6 0.77 1.78 291 [108 ] 134 5.36 15.7 5.80 10.1 165–5000 [58 ] 230 4.87 15.3 4.83 1.96 105–2000 [92 ] 47 3.33 12.0 2.10 0.71 170–500 [93 ] 8 3.29 14.2 2.64 1.43 298–973 [59 ] 4 3.39 13.1 0.57 2.48 303–363 [100 ] Xenon 3 8.35 17.6 4.75 7.55 313–363 [113 ] 29 5.84 14.9 8.18 2.90 50–3273 [26 ] 6 5.50 12.8 5.96 2.82 100–600 [29 ] 9 1.46 11.2 3.60 0.92 200–600 [60 ] 95 6.40 16.7 1.74 3.93 165–1500 [114 ] 24 8.00 19.0 1.20 5.10 350–1500 [104 ] 6 4.20 7.60 7.87 5.20 303–318 [105 ] 67 5.64 16.1 5.97 10.2 165–5000 [106 ] 2 9.00 19.0 3.90 7.01 302–793 [110 ] 1 0.80 9.10 4.95 2.06 311 [111 ] 1 7.30 16.3 3.43 6.00 302 [112 ] Average 707* 5.26 15.4 4.39 4.76
Overall 3352** 3.59 9.28 2.78 4.93
Number of data points for each noble gas.
Total number of data points for all noble gases.