Research Article
Nickel (II) and Iron (II) Complexes with Azole Derivatives: Synthesis, Crystal Structures and Antifungal Activities
Table 2
Selected bond lengths (Å) and bond angles (°) of 1 and 2.
| Complex ( ) | | | | Ni(1)-O(1) | 2.109(6) | O(1)-Ni(1)-N(1) | 89.8(3) | Ni(1)-N(1) | 2.105(8) | O(1)-Ni(1)-N(2) | 90.4(3) | Ni(1)-N(2) | 2.309(7) | O(1)-Ni(1)-O(1) | 180.0(2) | | | N(1)-Ni(1)-N(1) | 180.0(3) | | | N(1)-Ni(1)-N(2) | 100.8(3) | | | N(2)-Ni(1)-N(2) | 180.0(3) |
| Complex (2) | | | | Fe(1)-N(2) | 2.133(2) | N(2)-Fe(1)-N(1) | 73.66(8) | Fe(1)-N(4) | 2.107(3) | N(1)-Fe(1)-N(2) | 96.87(9) | Fe(1)-N(1) | 2.250(2) | N(2)-Fe(1)-N(4) | 87.61(1) | N(4)-C(008) | 1.159(4) | N(4)-Fe(1)-N(4) | 99.90(1) | S(2)-C(008) | 1.618(4) | N(4)-Fe(1)-N(1) | 90.90(1) | N(2)-N(3) | 1.351(3) | N(4)-Fe(1)-N(2) | 87.60(1) |
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Symmetry transformations used to generate equivalent atoms for ( ): , , , 1/2 −z, , , , 1/2 +x, 1/2 −y, 1/2 +z. (2): , , 1/2 −z, 1/2 +y, , 1/2 −x, , , , 1/2 +z, 1/2 −y.
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