Research Article
Synthesis, Crystal Structure, and Electrical Properties of a New Molybdylarsenate LiNa5K3Mo11As3O45
Table 1
Crystal data and the refinements details.
| Empirical formula | LiNa5K3Mo11As3O45 | Crystal system/space group/ | Triclinic/P-1/2 | (Å) | 10.550(2) | (Å) | 11.723(2) | (Å) | 17.469(3) | α (°) | 102.35(3) | β (°) | 87.61(2) | γ (°) | 111.03(3) | (Å3) | 1986.46(2) | μ (mm−1) | 6.39 | (g·cm−3)/formula weight (g/mol) | 3.78/2247.34 | Crystal size (mm)/Color | 0.2 × 0.3 × 0.5/yellow | Tmin/Tmax | 0.7026/0.8745 | Measured reflections | 9789 | Independent reflections/rint | 8557/0.0157 | Observed refl. with > 2σ() | 7730 | Data/restraints/parameters | 8557/2/619 | [ > 2σ()] | 0.028 | ()//(000) | 0.071/1.22/2072 | Δρmax/Δρmin (e·Å−3) | 1.56/−1.39 |
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