Research Article
Synthesis and Molecular Structure of cis-Tetracarbonyl[N-(diphenylphosphino-kP)-naphthalen-1-yl-P,P-diphenylphosphinous amide-kP]chromium(0)
Table 2
Selected bond lengths (Å) and bond angles (deg.) for 1.
| Cr1−C11 | 1.883(2) | C14−Cr1−C11 | 175.52(8) | Cr1−C12 | 1.859(2) | P1−Cr1−C12 | 100.26(7) | Cr1−C13 | 1.865(2) | P1−Cr1−C13 | 166.57(7) | Cr1−C14 | 1.881(2) | P1−Cr1−C14 | 88.05(6) | Cr1−P1 | 2.347(1) | P2−Cr1−C11 | 93.51(6) | Cr1−P2 | 2.347(1) | P2−Cr1−C12 | 168.99(6) | P1−N1 | 1.719(1) | P2−Cr1−C13 | 97.99(7) | P2−N1 | 1.722(1) | P2−Cr1−C14 | 90.89(6) | P1−C15 | 1.829(2) | P1−N1−P2 | 100.70(7) | P1−C21 | 1.818(2) | P1−Cr1−P2 | 68.74(3) | P2−C27 | 1.819(2) | P1−Cr1−C11 | 92.79(6) | P2−C33 | 1.830(2) | N1−P1−Cr1 | 94.26(5) | N1−C1 | 1.443(2) | N1−P2−Cr1 | 94.19(5) | C11−O1 | 1.136(2) | N1−P1−C15 | 105.49(7) | C12−O2 | 1.147(2) | N1−P1−C21 | 109.46(8) | C13−O3 | 1.140(2) | N1−P2−C27 | 106.55(8) | C14−O4 | 1.146(2) | N1−P2−C33 | 109.00(7) | C12−Cr1−C11 | 86.43(9) | C15−P1−C21 | 100.97(8) | C12−Cr1−C13 | 93.02(9) | C27−P2−C33 | 101.42(8) | C12−Cr1−C14 | 89.09(8) | angles at N1 | 359.91(9) | C13−Cr1−C11 | 90.05(9) | P2−Cr1−P1−N1 | −9.66(5) | C13−Cr1−C14 | 90.15(9) | C3−C2−C1−N1 | −177.61(2) |
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