Journal of Crystallography

Research Article

Structural Studies of and

Table 2

Selected bond lengths (Å) and angles (°) for [(py)2CdFe(CO)4]3.
Bond distances
Cd1–Fe12.6645(8)Cd2–N32.441(4)
Cd1–Fe22.6833(7)Cd2–N3A2.429(10)
Fe1–C11.747(7)C1–O11.158(7)
Fe1–C21.767(6)C2–O21.151(7)
Fe1–C31.784(7)C3–O31.156(7)
Fe1–C41.767(6)C4–O41.164(7)
Fe2–C51.765(6)C5–O51.162(7)
Fe2–C61.779(7)C6–O61.163(7)
Cd1–N12.424(4)Cd2–Fe12.6429(8)
Cd1–N22.444(5)  
Bond angles
Fe1–Cd1–Fe2135.31(3)Fe1–Cd2–Fe1′139.51(4)
Cd1–Fe1–Cd2102.52(3)Cd1–Fe2–Cd1′104.62(4)
C1–Fe1–C293.2(3)C5–Fe2–C5′92.7(4)
C3–Fe1–C4138.2(3)C6–Fe2–C6′135.8(4)
Cd1–Fe1–C2 79.8(2)N1–Cd1–N287.39(16)
Cd2–Fe1–C184.7(2)N3–Cd2–N3′88.2(4)
Cd1–Fe2–C5′81.6(2)N3′–Cd2–N3A86.7(2)