Research Article

Copper(II) Complexes of 2-(Methylthiomethyl)anilines: Spectral and Structural Properties and In Vitro Antimicrobial Activity

Table 2

H and C chemical shifts ( , ppm) of the ligands.

Ligands(C)1(C)2H (C)3H (C)4H (C)5H (C)6H (C)7H (C)8H9H (C)10

2MT(144.96)(121.19)7.05 d (130.49)6.76 t (117.96)7.14 t (128.21)6.71 d (116.15)3.71 s (35.14)2.01 s (14.32)4.06 s
4Me-2MT(142.62)(121.61)6.85 s (131.23)— (127.44)6.93 d (128.98)6.62 d (116.52)3.67 s (35.48)2.02 s (14.63)3.95 s 2.25 s (35.60)
4MeO-2MT(138.64)(123.71)6.70 d (116.46)— (152.21)6.64 s (113.45)6.64 d (117.41)3.64 s (35.48)1.99 s (14.57)3.81 s 3.73 s (55.56)
4Cl-2MT(143.85)(122.84)6.98 s (130.18)— (123.14)7.04 d (128.23)6.58 d (117.53)3.59 s (35.20)1.97 s (14.66)4.07 s
4Br-2MT(144.24)(109.72)7.13 s (132.83)— (123.47)7.18 d (130.99)6.60 d (117.82)3.60 s (35.00)1.98 s (14.57)4.08 s
4NO2-2MT(151.60)(119.95)7.96 s (126.68)— (138.42)8.02 d (125.08)6.67 d (114.76)3.70 s (34.94)2.00 s (14.57)4.76 s

s: singlet; d: doublet; t: triplet.