Research Article
Copper(II) Complexes of 2-(Methylthiomethyl)anilines: Spectral and Structural Properties and In Vitro Antimicrobial Activity
Table 4
Selected bond lengths
Å
and angles
°
for
CuCl
2(4NO
2-2MT)
(
2f).
| | Cu1–N1 | 2.0750(18) | Cu1–S1 | 2.3214(6) | | Cu1–Cl1 | 2.2554(6) | Cu1–Cl2* | 2.3184(5) | | Cu1–Cl2** | 2.6902(5) | Cl2–Cu1*** | 2.9321(5) | | S1–C8 | 1.798(2) | S1–C7 | 1.817(2) | | N1–C1 | 1.434(3) | C4–N2 | 1.464(3) | | N2–O2 | 1.203(3) | N2–O1 | 1.212(3) |
| | N1–Cu1–Cl1 | 176.82(5) | Cl2–Cu1–S1 | 163.90(2) | | S1–Cu1–Cl2 | 105.455(19) | N1–Cu1–Cl2 | 85.39(6) | | N1–Cu1–Cl2 | 88.60(5) | Cl1–Cu1–Cl2 | 93.19(2) | | Cl1–Cu1–Cl2 | 94.27(2) | Cl2–Cu1–Cl2 | 90.625(17) | | N1–Cu1–S1 | 91.93(5) | Cl1–Cu1–S1 | 85.69(2) | | Cu1–Cl2–Cu1 | 89.376(17) | C8–S1–C7 | 102.40(11) | | C8–S1–Cu1 | 105.25(9) | C7–S1–Cu1 | 104.90(7) | | C1–N1–Cu1 | 118.59(13) | O2–N2–O1 | 122.3(2) | | O2–N2–C4 | 118.5(2) | O1–N2–C4 | 119.2(2) |
|
|
; **; ***.
|
