Research Article
Kinetics of Thermolysis of Nickel(II) Perchlorate Complex with n-Propylamine
Table 3
Activation energy
, Arrhenius factor, and correlation coefficients
for the isothermal decomposition of the complex.
| Serial number | Model | | Slope | /kJmole−1 | | Mean deviation | Standard deviation |
| 1 | Power law3/4 | 1.1382 | 2128.2 | 17.7 | 0.9702 | 2.728 | 2.877 | 2 | Power law2/3 | 1.2143 | 1978.1 | 16.4 | 0.9641 | 2.613 | 2.756 | 3 | Power law1/2 | 0.6130 | 2148.7 | 17.8 | 0.9714 | 2.486 | 2.628 | 4 | Power law−1/2 | 0.0605 | 2207.1 | 18.3 | 0.9740 | 2.269 | 2.384 | 5 | Power law−1 | −0.0051 | 2224.6 | 18.5 | 0.9742 | 2.254 | 2.378 | 6 | Mampel | −1.1053 | 2275.1 | 18.9 | 0.9610 | 1.755 | 1.853 | 7 | a-e3/4 | 0.7241 | 2177.1 | 18.1 | 0.9748 | 2.570 | 2.711 | 8 | a-e2/3 | −0.0275 | 2249.8 | 18.7 | 0.9599 | 2.268 | 2.390 | 9 | a-e1/2 | −0.4144 | 2260.2 | 18.8 | 0.9605 | 2.085 | 2.201 | 10 | cs | 0.2240 | 2249.1 | 18.7 | 0.9686 | 2.393 | 2.525 | 11 | T-d-diff | 0.2629 | 2305.1 | 19.1 | 0.9614 | 2.470 | 2.605 | 12 | cc | 0.1869 | 2223.4 | 18.5 | 0.9713 | 2.349 | 2.478 | 13 | P-T | −1.6300 | 2237.5 | 18.6 | 0.9592 | 1.454 | 1.536 | 14 | G-B | 1.2040 | 2256.1 | 18.7 | 0.9698 | 2.891 | 3.049 |
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