Review Article
Copper Oxide Nanomaterials Prepared by Solution Methods, Some Properties, and Potential Applications: A Brief Review
Table 1
Summary on the effect of starting materials, solvents, and surfactants on morphology of CuO nanostructures.
| Morphology | Size | Solvent | Starting materials | Surfactant | Method | Reference |
| Hierarchical superstructure | Diameter: 200 nm; length: 600 nm SEM | Distilled water | Cu(CH3COO)2 NaOH |
Ethylene diamine-te tra-acetic acid disodium | Sonochemical | [11] |
| Cubic | 230 nm | Water |
Cu(CH3COO)2 NaOH | Without surfactant |
Microwave |
[18] | Sphere | 40 nm, 90 nm, and 140 nm (as the concentration of salt increases) | Ethylene glycol | PVP, CTAB |
| Nanoparticle | 50 nm XRD | Water | CuCl2, NH4OH | Thiourea | Chemical and annealing | [63] |
| Nanoparticle | 5–8 nm TEM and XRD | Ethanol | Cu(CH3COO)2 NaOH, methanol, and NH4OH | No | Alcothermal | [64] |
| Nanoparticle | 44 nm (XRD) 80 nm (TEM) | Deionized (DI) water | Cu(NO3)2 | Citric Acid; ethylene glycol | Sol-gel | [65] |
| Nanorod | Diameter: 50–100 nm Length: microns | 2-Propanol | Cu(NO3)2 | No | Solvothermal |
[50] | Nanosheet | Width: 1-2 mm; thickness: 20 nm | Ethanol |
| Nanoparticle | 22 nm | Deionized water | CuSO4 | Ascorbic acid NaBH4 | Chemical reduction |
[66] | 10 nm | Ethylene glycol | PVP |
| Flower-like | 400~600 nm | Deionized Water | Cu(CH3COO)2 | No | Hydrolyzing method | [67] |
| Nanoparticle | 3–9 nm (XRD) 11 nm (TEM) | Alcohol | Cu(CH3COO)2 | No | Alcohol thermal | [68] |
| Nanoplatelet | Lengths: 4-5 μm; thickness: 65–80 nm (SEM) | 1-Butyl-3-methyl imidazolium tetrafluoroborate BMIM]BF | Cu(NO3)2 NaOH | ([BMIM]BF4). It serves both as solvent and as surfactant | Hydrothermal | [69] |
| Nanoneedle | Length ~100 nm Diameter 10–20 nm (TEM) | Water | Cu(NO3)2 NaOH | Oleic acid Sodium oleate | Coprecipitation | [70] |
| Nanobelt | Length: 2.5–5 μm Width: 150–200 nm | Distilled water | CuSO4 NaOH | H2O2 | Hydrothermal | [71] |
| Nanoparticle | 100 nm (SEM) | Ethylene glycol | Cu(CH3COO)2 urea | No | Microwave | [72] |
|
|