Kelvin’s Dissymmetric Models and Consistency Conditions of Multicomponent Gas-Liquid Equilibrium and Capillary Condensation

<div>Functions <svg height="12.2089pt" id="M229" style="vertical-align:-2.503pt" version="1.1" viewbox="-0.0498162 -9.7059 26.8496 12.2089" width="26.8496pt" xmlns="http://www.w3.org/2000/svg" xmlns:xlink="http://www.w3.org/1999/xlink"><g transform="matrix(.013,0,0,-0.013,0,0)"><path d="M856 669C824 657 796 643 772 628C709 667 631 687 551 687C314 687 158 548 158 412C158 332 216 282 300 282C445 282 516 426 527 561H507C478 406 414 312 302 312C245 312 199 352 199 408C199 535 345 657 550 657C617 657 687 644 742 609C644 538 583 430 495 271C383 71 317 16 193 16C122 16 73 60 73 95H75C82 84 97 83 105 83C133 83 148 106 148 131C148 160 125 179 97 179C64 179 38 151 38 108C38 42 104 -15 211 -15C368 -15 496 71 610 302C672 426 704 522 770 588C803 559 825 518 825 465C825 382 787 316 731 316C710 316 697 328 697 345C697 358 700 380 733 399L723 417C688 398 665 367 665 338C665 303 688 272 737 272C821 272 886 359 886 447C886 516 850 572 797 612C816 627 836 639 863 650L856 669Z" id="g198-17"></path><glyph.data ascent="687" descent="-226" horiz-adv-x="910" vert-adv-y="910"></glyph.data></g><g transform="matrix(.013,0,0,-0.013,11.83,0)"><path d="M300 -147C201 -63 143 98 143 270S200 602 300 686L282 710C136 610 70 450 70 271V270C70 89 136 -72 282 -170L300 -147Z" id="g113-41"></path><glyph.data ascent="3473" descent="-2876" horiz-adv-x="346" vert-adv-y="346"></glyph.data></g><g transform="matrix(.013,0,0,-0.013,16.328,0)"><path d="M425 682C425 693 422 699 407 699C369 699 308 677 260 646C213 651 191 674 191 701C191 715 195 726 200 734L183 740C153 730 118 709 118 681C118 644 163 619 218 615C168 582 115 534 115 463C115 418 147 382 180 369C102 329 23 261 23 163C23 74 74 38 158 14C183 7 201 2 221 -2C279 -15 290 -33 290 -58C290 -94 251 -145 230 -169L252 -189C280 -171 367 -103 367 -25C367 20 333 51 266 68C245 73 218 80 191 89C139 106 107 135 107 192C107 261 161 329 221 355C248 350 281 347 314 347C330 347 370 388 370 406C370 418 366 422 352 422C321 422 280 413 255 407C218 413 192 448 192 493C192 544 229 588 266 610C309 610 354 615 376 623C397 631 425 651 425 682Z" id="g113-236"></path><glyph.data ascent="3473" descent="-2876" horiz-adv-x="448" vert-adv-y="448"></glyph.data></g><g transform="matrix(.013,0,0,-0.013,22.153,0)"><path d="M275 270C275 450 212 609 64 710L45 686C145 604 203 442 203 270S147 -63 45 -147L64 -170C213 -68 275 89 275 270Z" id="g113-42"></path><glyph.data ascent="3473" descent="-2876" horiz-adv-x="346" vert-adv-y="346"></glyph.data></g></svg> and <svg height="12.2089pt" id="M230" style="vertical-align:-2.503pt" version="1.1" viewbox="-0.0498162 -9.7059 24.005 12.2089" width="24.005pt" xmlns="http://www.w3.org/2000/svg" xmlns:xlink="http://www.w3.org/1999/xlink"><g transform="matrix(.013,0,0,-0.013,0,0)"><path d="M663 549C663 621 607 680 521 680C283 680 82 444 82 188C82 80 142 -15 258 -15C311 -15 361 -1 408 23C428 -8 451 -38 500 -38C535 -38 584 -16 633 44L618 58C582 23 543 10 516 10C485 10 469 28 454 52C564 133 637 268 637 396C637 502 561 542 497 542C414 542 336 469 336 362C336 331 339 284 371 232L393 242C369 289 366 322 366 347C366 448 430 506 494 506C539 506 586 470 586 396C586 266 508 157 469 118C458 106 446 97 435 86C418 115 396 142 349 142C313 142 284 123 241 84L254 67C283 90 305 96 330 96C359 96 375 77 390 53C350 29 307 15 256 15C179 15 142 78 142 150C142 331 347 645 517 645C590 645 624 603 643 547L663 549Z" id="g198-18"></path><glyph.data ascent="687" descent="-226" horiz-adv-x="692" vert-adv-y="692"></glyph.data></g><g transform="matrix(.013,0,0,-0.013,8.996,0)"><path d="M300 -147C201 -63 143 98 143 270S200 602 300 686L282 710C136 610 70 450 70 271V270C70 89 136 -72 282 -170L300 -147Z" id="g113-41"></path><glyph.data ascent="3473" descent="-2876" horiz-adv-x="346" vert-adv-y="346"></glyph.data></g><g transform="matrix(.013,0,0,-0.013,13.494,0)"><path d="M425 682C425 693 422 699 407 699C369 699 308 677 260 646C213 651 191 674 191 701C191 715 195 726 200 734L183 740C153 730 118 709 118 681C118 644 163 619 218 615C168 582 115 534 115 463C115 418 147 382 180 369C102 329 23 261 23 163C23 74 74 38 158 14C183 7 201 2 221 -2C279 -15 290 -33 290 -58C290 -94 251 -145 230 -169L252 -189C280 -171 367 -103 367 -25C367 20 333 51 266 68C245 73 218 80 191 89C139 106 107 135 107 192C107 261 161 329 221 355C248 350 281 347 314 347C330 347 370 388 370 406C370 418 366 422 352 422C321 422 280 413 255 407C218 413 192 448 192 493C192 544 229 588 266 610C309 610 354 615 376 623C397 631 425 651 425 682Z" id="g113-236"></path><glyph.data ascent="3473" descent="-2876" horiz-adv-x="448" vert-adv-y="448"></glyph.data></g><g transform="matrix(.013,0,0,-0.013,19.319,0)"><path d="M275 270C275 450 212 609 64 710L45 686C145 604 203 442 203 270S147 -63 45 -147L64 -170C213 -68 275 89 275 270Z" id="g113-42"></path><glyph.data ascent="3473" descent="-2876" horiz-adv-x="346" vert-adv-y="346"></glyph.data></g></svg> defined by (<a href="https://static.hindawi.com/articles/jther/volume-2016/3806364/figures/#EEq3.22">25</a>).</div>

Journal of Thermodynamics

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Figure 5

Figure 5: Kelvin’s Dissymmetric Models and Consistency Conditions of Multicomponent Gas-Liquid Equilibrium and Capillary Condensation 