Research Article

Kelvin’s Dissymmetric Models and Consistency Conditions of Multicomponent Gas-Liquid Equilibrium and Capillary Condensation

Table 1

Parameters of dissymmetric models for pure components used to calculate binary mixtures.


K

bar (calculated by PR EOS)

bar

 m3/mol

bar

bar−1

2-Methylpentane, C6H14 328.15 0.809 60.7 129.9 6565.0 5.292
Heptane, C7H16 328.15 0.232 54.8 149.7 6832.1 5.347
Octane, C8H18 328.15 0.089 49.8 169.5 6792.8 5.550
Pentane, C5H12 328.15 1.580 67.4 109.4 7357.9 5.143
Benzene, C6H6 328.15 0.380 97.52 85.5 13550 2.786

Butane, C4H10 377.6 16.82 76 123.3 3992.4 7.028
Decane, C10H22 377.6 0.117 42.2 219.6 5721.1 6.497