Research Article
Kelvin’s Dissymmetric Models and Consistency Conditions of Multicomponent Gas-Liquid Equilibrium and Capillary Condensation
Table 2
Parameters of fitting pure components used to calculate ternary mixtures.
| | |
K |
bar (calculated by PR EOS) |
bar |
m3/mol |
bar |
bar−1 |
| | Propane, C3H8 | 300 | 9.870 | 84 | 84.4 | 5726.2 | 5.253 | | Pentane, C5H12 | 300 | 0.732 | 67.4 | 109.4 | 7357.9 | 4.765 | | Decane, C10H22 | 300 | 0.0021 | 42.2 | 206.7 | 7510.2 | 5.531 |
| | Hydrogen Sulfide, H2S | 290 | 14.155 | 180.08 | 37.5 | 13919 | 2.238 | | Propane, C3H8 | 290 | 7.600 | 84.02 | 81.2 | 6183 | 4.977 | | Pentane, C5H12 | 290 | 0.501 | 67.40 | 107.8 | 7669 | 4.650 |
| | Argon, Ar | 112 | 16.517 | 67.92 | 42.41 | 32847 | 8.410 | | Nitrogen, N2 | 112 | 7.582 | 97.20 | 28.14 | 7072.7 | 4.390 | | Methane, CH4 | 112 | 1.048 | 91.60 | 32.77 | 8915.3 | 3.905 |
| | R22, CHF2Cl | 273.2 | 4.29 | 99.8 | 63.83 | 8594 | 3.61 | | Nitrogen, N2 | 273.2 | — | 732.71 | 47.44 | 194.1 | 16.76 | | Carbon Dioxide, CO2 | 273.2 | 34.82 | 147.55 | 46.33 | 7498.3 | 3.71 |
| | R30, CH2Cl2 | 318.15 | 1.266 | 126 | 63.35 | 1359.9 | 2.585 | | R10, CCl4 | 318.15 | 0.351 | 91.2 | 92.37 | 1077.5 | 3.395 | | R20, CHCl3 | 318.15 | 0.567 | 107.4 | 76.34 | 1247 | 2.898 |
| | R142b, CH3-CF2Cl | 323.25 | 6.647 | 81.1 | 91.96 | 6278 | 4.949 | | R140a, CCl3-CH3 | 323.25 | 0.1481 | 102.8 | 87.09 | 13244 | 2.861 | | R141b, CH3-CFCl2 | 323.25 | 1.8055 | 83.88 | 92.46 | 8314 | 4.074 |
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