Advances in Chemistry / 2014 / Article / Tab 1

Research Article

Cobalt(II) and Manganese(II) Complexes of Novel Schiff Bases, Synthesis, Charcterization, and Thermal, Antimicrobial, Electronic, and Catalytic Features

Table 1

Electrochemical data of the title compounds.

CompoundScan rate (mV/s) () (V) (V) (V)

L11000.87, −1.18 (−0.57, 0.88)0.880.01
2500.87, −0.06, −1.24 (−0.48, 1.00)0.13
5000.94, −0.08, −1.32 (−0.42, 1.04)0.15
7500.90, −0.12, −1.40 (−0.38, 1.12)0.22
10000.90, −0.14, −1.42 (−0.35, 1.14)0.24

[Co(L1)(H2O)2]2AcO1000.72, −1.14 (−0.58, 0.80)0.12
2500.76, −1.28 (−0.50, 0.93)0.17
5000.93, −1.40 (−0.46, 1.03)0.16
7500.97, −1.47 (−0.46, 1.07)0.21
10000.87, −1.54 (−0.42, 1.17)0.30

[Mn(L1)(H2O)2]2AcO1000.98, −1.11 (−0.52, 1.07)0.09
2500.98, −1.13 (−0.54, 1.02)0.04
5000.97, −1.28 (−0.40, 1.08)0.13
7500.96, −1.41 (−0.33, 1.26)0.30
10000.97, −1.47 (−0.26, 1.22)0.25

L21000.09, −0.90 (−0.56, −0.01, 0.82)−0.10
2500.91, 0.03, −1.01 (−0.53, 0.93)0.920.02
5000.94, −0.02, −1.09 (−0.50, 0.95)0.950.01
7500.98, −1.12 (−0.44, 0.99)0.990.01
10000.96, −1.31 (−0.35, 0.99)0.980.03

[Co(L2)(H2O)2]2AcO1001.13, −0.03, −0.91 (−0.53, 0.14, 1.25)0.17
2500.99, −0.07, −0.96 (−0.47, 0.20, 1.10)0.720.12
5000.96, −0.08, −1.02 (−0.50, 1.13)0.760.17
7500.95, −1.19 (−0.41, 1.10)0.15
10000.97, −1.42 (−0.27, 1.10)0.13

[Mn(L2)(H2O)2]2AcO1001.10, −0.05, −0.92 (−0.54, 1.19)0.20
2500.96, 0.01, −1.00 (−0.49, 1.18)0.750.22
5000.97, 0.13, −1.12 (−0.42, 1.07)0.12
7500.96, −1.22 (−0.30, 1.11)0.15
10000.93, −1.43 (−0.24, 1.15)0.22