Mycotoxin Analysis: New Proposals for Sample Treatment
Table 3
Monitored ions of target analytes and MS/MS parameters.
Analyte
Retention time (min)
Precursor ion ()
Molecular ion
DPa
EPa
CEPa
Product ionsb
CEna
CXPa
NIV
1.36
313.1
[M + H]+
41.0
5.0
14.0
174.9 (Q)
17.0
4.0
128.0 (I)
75.0
6.0
DON
1.70
297.1
[M + H]+
36.0
5.5
16.0
249.2 (Q)
17.0
4.0
161.0 (I)
29.0
4.0
F-X
2.02
355.1
[M + H]+
26.0
12.0
18.0
174.7 (Q)
23.0
4.0
137.1 (I)
31.0
4.0
AFG2
2.52
331.1
[M + H]+
61.0
6.0
42.0
245.1 (Q)
39.0
4.0
313.1 (I)
27.0
6.0
AFG1
2.61
329.0
[M + H]+
76.0
9.5
16.0
243.1 (Q)
39.0
6.0
311.1 (I)
29.0
6.0
AFB2
2.72
315.1
[M + H]+
81.0
4.0
34.0
286.9 (Q)
33.0
6.0
259.0 (I)
39.0
8.0
AFB1
2.79
313.1
[M + H]+
46.0
12.0
26.0
241.0 (Q)
41.0
4.0
284.9 (I)
39.0
4.0
CIT
2.90
251.2
[M + H]+
26.0
11.0
18.0
233.0 (Q)
23.0
23.0
204.8 (I)
73.0
10.0
HT-2
3.18
442.0
[M + NH4]+
21.0
5.5
21.0
262.8 (Q)
22.0
8.0
215.4 (I)
19.0
4.0
FB1
3.24
722.2
[M + H]+
71.0
10.0
30.0
334.2 (Q)
51.0
6.0
352.2 (I)
47.0
6.0
T-2
3.44
484.0
[M + NH4]+
21.0
10.0
22.0
215.0 (Q)
22.0
4.0
185.0 (I)
29.0
4.0
ZEN
3.71
319.0
[M + H]+
26.0
8.0
20.0
282.9 (Q)
19.0
4.0
301.0 (I)
15.0
10.0
OTA
3.76
404.0
[M + H]+
41.0
7.5
16.0
238.9 (Q)
31.0
6.0
102.1 (I)
91.0
6.0
FB2
3.86
706.2
[M + H]+
71.0
10.5
20.0
336.3 (Q)
43.0
14.0
318.3 (I)
45.0
12.0
STE
3.88
325.1
[M + H]+
66.0
3.5
26.0
281.0 (Q)
43.0
4.0
310.0 (I)
37.0
4.0
(DP) Declustering potential, (EP) entrance potential, (CEP) collision cell entrance potential, (CXP) collision cell exit potential, and (CEn) collision energy. All expressed in voltage.
bProduct ions: (Q) transition used for quantification and (I) transition employed to confirm the identification.
