Table 3: Monitored ions of target analytes and MS/MS parameters.

AnalyteRetention time (min)Precursor ion ()Molecular ionDPaEPaCEPaProduct ionsbCEnaCXPa

NIV1.36313.1[M + H]+41.05.014.0174.9 (Q)17.04.0
128.0 (I)75.06.0

DON1.70297.1[M + H]+36.05.516.0249.2 (Q)17.04.0
161.0 (I)29.04.0

F-X2.02355.1[M + H]+26.012.018.0174.7 (Q)23.04.0
137.1 (I)31.04.0

AFG22.52331.1[M + H]+61.06.042.0245.1 (Q)39.04.0
313.1 (I)27.06.0

AFG12.61329.0[M + H]+76.09.516.0243.1 (Q)39.06.0
311.1 (I)29.06.0

AFB22.72315.1[M + H]+81.04.034.0286.9 (Q)33.06.0
259.0 (I)39.08.0

AFB12.79313.1[M + H]+46.012.026.0241.0 (Q)41.04.0
284.9 (I)39.04.0

CIT2.90251.2[M + H]+26.011.018.0233.0 (Q)23.023.0
204.8 (I)73.010.0

HT-23.18442.0[M + NH4]+21.05.521.0262.8 (Q)22.08.0
215.4 (I)19.04.0

FB13.24722.2[M + H]+71.010.030.0334.2 (Q)51.06.0
352.2 (I)47.06.0

T-23.44484.0[M + NH4]+21.010.022.0215.0 (Q)22.04.0
185.0 (I)29.04.0

ZEN3.71319.0[M + H]+26.08.020.0282.9 (Q)19.04.0
301.0 (I)15.010.0

OTA3.76404.0[M + H]+41.07.516.0238.9 (Q)31.06.0
102.1 (I)91.06.0

FB23.86706.2[M + H]+71.010.520.0336.3 (Q)43.014.0
318.3 (I)45.012.0

STE3.88325.1[M + H]+66.03.526.0281.0 (Q)43.04.0
310.0 (I)37.04.0

(DP) Declustering potential, (EP) entrance potential, (CEP) collision cell entrance potential, (CXP) collision cell exit potential, and (CEn) collision energy. All expressed in voltage.
bProduct ions: (Q) transition used for quantification and (I) transition employed to confirm the identification.