Research Article
Inhibition of Aluminium Corrosion in 1.0 M HCl by Caffeine: Experimental and DFT Studies
Table 1
Parameters of the modified Langmuir adsorption isotherms.
| Isotherm | Equation | (K) | | Slope | Intercept | (×103 M) | (kJmol−1) |
| Villamil et al. | | 303 | 0.994 | 1.3542 | 0.0007 | 2.768 | | 308 | 0.999 | 1.6943 | 0.0005 | 5.648 | | 313 | 0.998 | 1.8394 | 0.0007 | 4.598 | | 318 | 0.994 | 1.9882 | 0.0012 | 3.314 | | 323 | 0.995 | 2.3771 | 0.0014 | 3.962 | |
| El-Awady |
| 303 | 0.999 | 0.3421 | 1.1085 | 1.738 | | 308 | 0.996 | 0.2442 | 0.6466 | 0.444 | | 313 | 0.978 | 0.2413 | 0.5539 | 0.197 | | 318 | 0.968 | 0.2435 | 0.4809 | 0.094 | | 323 | 0.992 | 0.2226 | 0.2950 | 0.021 | |
|
|